3,6-Carbazoylene Octaphyrin (1.0.0.0.1.0.0.0) and Its Bis-BF2 Complex.
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DOI: 10.1021/jacs.2c01240
Abstract: 3,6-Carbazole precursors were used to prepare an octaphyrin. The conformation and electronic structure of the system could be modulated through trifluoroacetate (TFA) protonation and BF2 complexation. The resulting nonaromatic macrocyclic complexes, 2-2TFA and 2-2BF2, displayed… read more here.
Keywords: octaphyrin bis; carbazoylene octaphyrin; bf2; bf2 complex ... See more keywords
[38]Octaphyrin bis-Sn(IV) complexes with unique coordination geometries
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DOI: 10.1142/s1088424621500103
Abstract: Metal complexation of octaphyrin(1.1.1.1.1.1.1.1) triggers unique ring-fixation aptitudes or unexpected rearrangement (cleavage) reactions. In this paper, a unique complexation behavior of [38]octa... read more here.
Keywords: complexes unique; coordination geometries; bis complexes; unique coordination ... See more keywords