Chromium N-phosphinoamidine ethylene tri-/tetramerization catalysts: Designing a step change in 1-octene selectivity
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DOI: 10.1016/j.jcat.2020.10.021
Abstract: Abstract Steric reduction principles were applied in N-phosphinoamidine ligand (PN) design to significantly improve 1-octene selectivity in ethylene tri-/tetramerization chromium catalysis. Novel phosphole- and phospholane-based PN-ligands were prepared and used to synthesize discrete chromium complexes… read more here.
Keywords: tri tetramerization; ethylene tri; octene selectivity; selectivity ... See more keywords