Living Polymerization Caught in the Act: Direct Observation of an Arrested Intermediate in Metathesis Polymerization.
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DOI: 10.1021/jacs.9b04019
Abstract: Understanding the stability and reactivity of the propagating species is critical in living polymerization. Therefore, most living olefin metathesis polymerizations require the stabilization of the catalyst by coordination of external ligands containing Lewis basic heteroatoms,… read more here.
Keywords: metathesis polymerization; polymerization; olefin chelation; living polymerization ... See more keywords