Ketone-Olefin Coupling of Aliphatic and Aromatic Carbonyls Catalyzed by Excited-State Acridine Radicals.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c04822
Abstract: Ketone-olefin coupling reactions are common methods for the formation of carbon-carbon bonds. This reaction class typically requires stoichiometric or super stoichiometric quantities of metal reductants, and catalytic variations are limited in application. Photoredox catalysis has… read more here.
Keywords: olefin coupling; state acridine; excited state; ketone olefin ... See more keywords
Catalytic defluorinative ketyl–olefin coupling by halogen-atom transfer
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc02732a
Abstract: Ketyl–olefin coupling reactions stand as one of the fundamental chemical transformations in synthetic chemistry and have been widely employed in the generation of complex molecular architectures and natural product synthesis. However, catalytic ketyl–olefin coupling, until… read more here.
Keywords: ketyl olefin; olefin coupling; halogen atom; chemistry ... See more keywords