Palladium-Catalyzed meta-C-H Olefination of Arene-Tethered Diols Directed by Well-Designed Pyrimidine-Based Group.
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DOI: 10.1021/acs.orglett.9b00433
Abstract: The palladium-catalyzed meta-olefination of arene-tethered diols attached to a well-designed pyrimidine moiety is presented. Applications of the protocol are illustrated by the synthesis of various diol-based natural products, such as coumarins, phenylpropanoids, stilbenes, and chalcones.… read more here.
Keywords: olefination; palladium catalyzed; arene tethered; meta olefination ... See more keywords