Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’
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DOI: 10.1016/j.mencom.2017.01.010
Abstract: Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective… read more here.
Keywords: zirconocene; catalytic oligomerization; olefins presence; dimethylfulvene dimer ... See more keywords
Metal-free photocatalytic hydrosilylation of olefins in the presence of photoinitiators
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DOI: 10.1039/d0nj06075e
Abstract: A convenient metal-free photocatalytic hydrosilylation of a variety of linear and cyclic alkenes has been investigated. It was found that the free radical type photoinitiator Irgacure 2959 had a better effect on the hydrosilylation reaction;… read more here.
Keywords: hydrosilylation; free photocatalytic; hydrosilylation olefins; olefins presence ... See more keywords