Pd-Catalyzed TBHP-Mediated Selective Wacker-Type Oxidation and Oxo-acyloxylation of Olefins Using a 2-(1H-Indazol-1-yl)quinoline Ligand.
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DOI: 10.1021/acs.orglett.3c00326
Abstract: Pd(II)-catalyzed oxidation of terminal olefins to methyl ketones has emerged as an attractive strategy for organic synthesis. Here we report the Pd(II)-catalyzed selective oxidation of olefins using tert-butyl hydroperoxide as the oxidant and 2-(1H-indazol-1-yl)quinoline as… read more here.
Keywords: oxidation; quinoline ligand; olefins using; oxo acyloxylation ... See more keywords
B(C6F5)3-Catalyzed Regioselective Deuteration of Terminal Olefins Using D2O as the Deuterium Source.
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DOI: 10.1021/acs.orglett.5c01101
Abstract: The selective deuteration of α-alkyl olefins is challenging due to their polymerization tendency and limited catalytic options. Herein, we report the B(C6F5)3-catalyzed deuteration of terminal olefins using D2O as the deuterium source. This approach efficiently… read more here.
Keywords: olefins using; c6f5 catalyzed; deuteration; deuteration terminal ... See more keywords