Electronic Structure and Reactivity Studies of a Nonsymmetric One-Electron Oxidized CuII Bis-phenoxide Complex.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica chimica acta"
DOI: 10.1016/j.ica.2017.09.042
Abstract: The tetradentate mixed imino/amino phenoxide ligand (N-(3,5-di-tert-butylsalicylidene)-N'-(2-hydroxyl-3,5-di-tert-butylbenzyl))-trans-1,2-cyclohexanediamine (salalen) was complexed with CuII, and the resulting Cu complex (2) was characterized by a number of experimental techniques and theoretical calculations. Two quasi-reversible redox processes for 2,… read more here.
Keywords: oxidized cuii; electronic structure; one electron; electron ... See more keywords
One-electron oxidation of chloroquine, cymanquine, and related aminoquinolines in nonaqueous media
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2017.06.041
Abstract: The anodic oxidation of a series of secondary-amine-substituted chloroquinoline derivatives, 1–5, has been studied in dichloromethane/0.05 M [NBu4][B(C6F5)4]. Compounds 4 and 5 contain organometallic moieties of the cymantrene family as part of the amine group.… read more here.
Keywords: one electron; secondary amine; electron oxidation; oxidation ... See more keywords
One electron oxidation of ascorbic acid facilitated by ionic liquid-doped poly (3, 4-ethylenedioxythiophene) as artificial enzyme
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2020.114702
Abstract: Abstract Ascorbic acid (AA) play vital roles in various physiological processes and its two-electron oxidation pathway is typically documented. In this study, we reported that ionic liquid (IL) 1-ethyl-3-methylimidazolium bis(trifluoromethyl sulfonyl) imide served as unique… read more here.
Keywords: electron oxidation; ascorbic acid; artificial enzyme; one electron ... See more keywords
Interaction of Quinone-Related Electron Acceptors with Hydropersulfide Na2S2: Evidence for One-Electron Reduction Reaction.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical research in toxicology"
DOI: 10.1021/acs.chemrestox.8b00158
Abstract: We previously reported that 9,10-phenanthraquinone (9,10-PQ), an atmospheric electron acceptor, undergoes redox cycling with dithiols as electron donors, resulting in the formation of semiquinone radicals and monothiyl radicals; however, monothiols have little reactivity. Because persulfide… read more here.
Keywords: electron reduction; one electron; electron acceptors; reaction ... See more keywords
One-Electron Oxidant-Induced Transformations of Aromatic Alcohol to Ketone Moieties in Dissolved Organic Matter Increase Trichloromethane Formation.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c06425
Abstract: Radicals in advanced oxidation processes (AOPs) degrade micropollutants during water and wastewater treatment, but the transformation of dissolved organic matter (DOM) may be equally important. Ketone moieties in DOM are known disinfection byproduct precursors, but… read more here.
Keywords: one electron; ketone; aromatic alcohol; electron ... See more keywords
Photoexcitation and One-Electron Reduction Processes of a CO2 Photoreduction Dyad Catalyst Having a Zinc(II) Porphyrin Photosensitizer
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c02271
Abstract: We have explored the photophysical properties and one-electron reduction process in the dyad photocatalyst for CO2 photoreduction, ZnP-phen=Re, in which the catalyst of fac-[Re(1,10-phenanthoroline)(CO)3Br] is directly connected with the photosensitizer of zinc(II) porphyrin (ZnP), using… read more here.
Keywords: spectroscopy; one electron; reduction; electron reduction ... See more keywords
Does the Traditional Band Picture Correctly Describe the Electronic Structure of n-Doped Conjugated Polymers? A TD-DFT and Natural Transition Orbital Study
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Chemical Theory and Computation"
DOI: 10.1021/acs.jctc.4c00817
Abstract: Doped conjugated polymers have a variety of potential applications in thermoelectric and other electronic devices, but the nature of their electronic structure is still not well understood. In this work, we use time-dependent density functional… read more here.
Keywords: spectroscopy; one electron; conjugated polymers; doped conjugated ... See more keywords
One-Electron (2c/1e) Tin···Tin Bond Stabilized by ortho-Phenylenediamido Ligands.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c11893
Abstract: Odd-electron bonds, i.e., the two-center, three-electron (2c/3e), or one-electron (2c/1e) bonds, have attracted tremendous interest owing to their novel bonding nature and radical properties. Herein, complex [K(THF)6][LSn:···Sn:L] (1), featuring the first and unsupported 2c/1e Sn···Sn… read more here.
Keywords: electron tin; one electron; electron; tin tin ... See more keywords
Multireference Theory of Scanning Tunneling Spectroscopy Beyond One-Electron Molecular Orbitals: Can We Image Molecular Orbitals?
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c08166
Abstract: Recent progress in on-surface chemistry has enabled the synthesis of novel polyradical molecules with interesting electronic structure, which are hardly available in solution chemistry. Moreover, the possibility to characterize their electronic structure with scanning tunneling… read more here.
Keywords: spectroscopy; chemistry; one electron; molecular orbitals ... See more keywords
One-Electron Boron–Carbon Triel Bonding
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c13589
Abstract: Aiming to interrogate the possibility of heteronuclear B–C one-electron σ-bonding, we have prepared a naphthalene-based platform ([5]+) decorated at its peri-positions by a carbenium and a boryl unit separated by a B–C distance of 2.994(4)… read more here.
Keywords: one electron; boron carbon; triel; bond ... See more keywords
Bambusuril as a One-Electron Donor for Photoinduced Electron Transfer to Methyl Viologen in Mixed Crystals.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b08589
Abstract: Methyl viologen hexafluorophosphate (MV2+·2PF6-) and dodecamethylbambus[6]uril (BU6) form crystals in which the layers of viologen dications alternate with those of a 1:2 supramolecular complex of BU6 and PF6-. This arrangement allows for a one-electron reduction… read more here.
Keywords: photoinduced electron; one electron; electron transfer; methyl viologen ... See more keywords