Acetylene based short route from 2,2,6,6-tetramethylpiperidin-4-one oxime to 2-(pyrazol-5-yl)-4,5,6,7-tetrahydropyrrolo[3,2-c]pyridines
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DOI: 10.1016/j.mencom.2019.11.018
Abstract: Pharmaceutically relevant substituted 2-(pyrazol-5-yl)-4,5,6,7-tetrahydropyrrolo [3,2-c]pyridines have been assembled in good to excellent yields via the reaction of 2,2,6,6-tetramethylpiperidin-4-one oxime with acetylene, cross-coupling of the resulting 4,4,6,6-tetramethyl-4,5,6,7 tetrahydropyrrolo[3,2-c]pyridines with aroylbromoacetylenes, and reaction of the formed 2-(aroylethynyl)-4,4,6,6-tetramethyl-4,5,6,7-tetrahydropyrrolo[3,2-c]pyridines… read more here.
Keywords: pyrazol tetrahydropyrrolo; one oxime; tetramethylpiperidin one; tetrahydropyrrolo ... See more keywords
Flotation performance and adsorption mechanism of novel 1-(2-hydroxyphenyl)hex-2-en-1-one oxime flotation collector to malachite
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DOI: 10.1016/s1003-6326(20)65421-8
Abstract: Abstract A novel collector 1-(2-hydroxyphenyl)hex-2-en-1-one oxime (HPHO) was synthesized from 2-hydroxy acetophenone and butyraldehyde. Its flotation performance and adsorption mechanism to malachite were investigated by flotation test, zeta potential, Fourier transform infrared (FTIR) and X-ray… read more here.
Keywords: oxime; adsorption; one oxime; hydroxyphenyl hex ... See more keywords
Synthesis, Crystal Structure, and Characterization of Energetic Salts Based on 3,5-Diamino-4H-Pyrazol-4-One Oxime
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DOI: 10.3390/molecules28010457
Abstract: In order to broaden the study of energetic cations, a cation 3,5-diamino-4H-pyrazol-4-one oxime (DAPO) with good thermal stability was proposed, and its three salts were synthesized by a simple and efficient method. The structures of… read more here.
Keywords: pyrazol one; one oxime; diamino pyrazol; energetic salts ... See more keywords
Evaluation of Nitric Oxide-Donating Properties of 11H-indeno[1,2-b]quinoxalin-11-one Oxime (IQ-1) by Electron Paramagnetic Resonance Spectroscopy
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DOI: 10.3390/molecules29163820
Abstract: IQ-1 (11H-indeno[1,2-b]quinoxalin-11-one oxime) is a specific c-Jun N-terminal kinase (JNK) inhibitor with anticancer and neuro- and cardioprotective properties. Because aryloxime derivatives undergo cytochrome P450-catalyzed oxidation to nitric oxide (NO) and ketones in liver microsomes, NO… read more here.
Keywords: spectroscopy; one oxime; 11h indeno; indeno quinoxalin ... See more keywords