Photoredox-Catalyzed C-H Trideuteromethylation of Quinoxalin-2(1H)-ones with CDCl3 as the "CD3" source.
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DOI: 10.1021/acs.orglett.2c02439
Abstract: Herein, readily available and inexpensive CDCl3 was first identified as a new trideuteromethylation reagent under photoredox-catalyzed conditions. Thus, a facile photocatalytic protocol for the C-H trideuteromethylation of quinoxalin-2(1H)-one was achieved. This operationally straightforward transformation displays… read more here.
Keywords: catalyzed trideuteromethylation; quinoxalin ones; trideuteromethylation; trideuteromethylation quinoxalin ... See more keywords