The Metal or the Ligand? The Preferred Locus for Redox Changes in Oxygen Atom Transfer Reactions of Rhenium Amidodiphenoxides.
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DOI: 10.1021/jacs.7b00985
Abstract: The rhenium(V) oxo complex oxo(triphenylphosphine) (bis(3,5-di-tert-butyl-2-phenoxo)amido)rhenium(V), (ONOCat)ReO(PPh3), reacts with molecular oxygen to give triphenylphosphine oxide and the dimeric rhenium(VII) complex fac,anti-(ONOCat)Re(O)(μ-O)2Re(O)(ONOCat). The ONO ligand adopts an unusual fac geometry, presumably to maximize π donation to… read more here.
Keywords: atom transfer; onocat; oxygen atom; transfer ... See more keywords