Characterization and chemical reactivity of room-temperature-stable MnIII–alkylperoxo complexes
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DOI: 10.1039/d1sc01976g
Abstract: While alkylperoxomanganese(iii) (MnIII–OOR) intermediates are proposed in the catalytic cycles of several manganese-dependent enzymes, their characterization has proven to be a challenge due to their inherent thermal instability. Fundamental understanding of the structural and electronic… read more here.
Keywords: mniii oor; mniii; reactivity; oor complexes ... See more keywords