Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice.
Sign Up to like & getrecommendations! Published in 2019 at "ChemPlusChem"
DOI: 10.1002/cplu.201900017
Abstract: A new type of open-cage [60]fullerene was prepared starting from our previously reported open-cage [60]fullerenes containing hydroxy and tert-butylperoxo groups, and an iminofuranone moiety on the rim of the orifice. The key reactions are alcoholysis… read more here.
Keywords: open cage; cage fullerenes; synthesis open; cage ... See more keywords
Probing the Structure-Property Relationships of Na+···Cl-@C50N5H5 under the External Electric Field.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02734
Abstract: Endohedral open-cage fullerenes are one of the attractive types of fullerenes due to their interesting electronic properties which make it potentially promising for applications in molecular electronics. In this paper, a novel structure of Na+···Cl-@C50N5H5… read more here.
Keywords: electric field; structure; external electric; open cage ... See more keywords
Promoting the Efficiency and Stability of Nonfullerene Organic Photovoltaics by Incorporating Open-Cage [60]Fullerenes in the Nonfullerene Nanocrystallites.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c06354
Abstract: The device efficiency of PM6:Y6-based nonfullerene organic solar cells is fast advanced recently. To maintain organic solar cells (OSCs) with high power conversion efficiency over 16% in long-term operation, however, remains a challenge. Here, a… read more here.
Keywords: pm6; stability; efficiency; open cage ... See more keywords
Aromaticity in Fully π-Conjugated Open-Cage Molecules.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10859
Abstract: Although aromaticity in 2D π-conjugated monocyclic and polycyclic molecules has been intensively studied, aromaticity in 3D fully π-conjugated molecular cages remains largely unexplored mainly due to the synthetic challenges. Herein, we report the facile synthesis… read more here.
Keywords: conjugated open; aromaticity fully; cage; aromaticity ... See more keywords
Synthesis and Structure of an Open-cage C69O Derivative
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DOI: 10.1246/cl.161178
Abstract: A novel open-cage fullerene derivative having a C69O framework was synthesized, demonstrating that the reactivity of an open-cage C70 with a tetraketone moiety was quite different compared with its C60 analogue. The structure of the… read more here.
Keywords: cage; structure open; open cage; cage c69o ... See more keywords
Enhanced Open-Circuit Voltage in Perovskite Solar Cells with Open-Cage [60]Fullerene Derivatives as Electron-Transporting Materials
Sign Up to like & getrecommendations! Published in 2019 at "Materials"
DOI: 10.3390/ma12081314
Abstract: The synthesis, characterization, and incorporation of open-cage [60]fullerene derivatives as electron-transporting materials (ETMs) in perovskite solar cells (PSCs) with an inverted planar (p-i-n) structure is reported. Following optical and electrochemical characterization of the open-cage fullerenes… read more here.
Keywords: fullerene derivatives; derivatives electron; cage fullerene; open cage ... See more keywords
Preparation of Tri(alkenyl)functional Open-Cage Silsesquioxanes as Specific Polymer Modifiers
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DOI: 10.3390/polym12051063
Abstract: The scientific reports on polyhedral oligomeric silsesquioxanes are mostly focused on the formation of completely condensed T8 cubic type structures and recently so-called double-decker derivatives. Herein, we report on efficient synthetic routes leading to trifunctionalized,… read more here.
Keywords: methodology; cage silsesquioxanes; tri alkenyl; open cage ... See more keywords