Photoluminescence and Magnetism Study of Blue Light Emitting the Oxygen-Bridged Open-Cubane Cobalt(II) Cluster
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Cluster Science"
DOI: 10.1007/s10876-018-1406-2
Abstract: A new cubane-based cobalt(II) cluster, [Co4L4] (1), where H2L = 2-((E)-(2-hydroxyethylimino) methyl)-4-chlorophenol has been prepared using a solvothermal process and characterized by structural, optical and magnetism. The crystal structure of 1 consists of a tetranuclear Co4O4 core… read more here.
Keywords: magnetism; cobalt; cubane; cobalt cluster ... See more keywords
A tetra Co(II/III) complex with an open cubane Co4O4 core and square-pyramidal Co(II) and octahedral Co(III) centres: bifunctional electrocatalytic activity towards water splitting at neutral pH.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04086c
Abstract: The reaction of 2,6-diformyl-4-methylphenol, 4-methoxybenzoylhydrazine and Co(OAc)2·4H2O in 1 : 2 : 2 mole ratio in methanol under aerobic conditions produced in 61% yield a tetranuclear complex having the molecular formula [CoIICoIII(μ-OAc)(μ3-OH)(μ-L)]2 where OAc- and L3- represent acetate and… read more here.
Keywords: electrocatalytic activity; co4o4; square pyramidal; iii ... See more keywords
Synthesis of Novel Tetra(µ3-Methoxo) Bridged with [Cu(II)-O-Cd(II)] Double-Open-Cubane Cluster: XRD/HSA-Interactions, Spectral and Oxidizing Properties
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DOI: 10.3390/ijms21228787
Abstract: A new double-open-cubane core Cd(II)-O-Cu(II) bimetallic ligand mixed cluster of type [Cl2Cu4Cd2(NNO)6(NN)2(NO3)2].CH3CN was made available in EtOH/CH3CN solution. The 1-hydroxymethyl-3,5-dimethylpyrazole (NNOH) and 3,5-dimethylpyrazole (NNH) act as N,O-polydentate anion ligands in coordinating the Cu(II) and Cd(II)… read more here.
Keywords: cluster; double open; xrd; cubane cluster ... See more keywords