Prussian Blue Nanocubes with an Open Framework Structure Coated with PEDOT as High-Capacity Cathodes for Lithium-Sulfur Batteries.
Sign Up to like & getrecommendations! Published in 2017 at "Advanced materials"
DOI: 10.1002/adma.201700587
Abstract: It is shown that Prussian blue analogues (PBAs) can be a very competitive sulfur host for lithium-sulfur (Li-S) batteries. Sulfur stored in the large interstitial sites of a PBA host can take advantage of reversible… read more here.
Keywords: open framework; sulfur batteries; blue nanocubes; lithium sulfur ... See more keywords
A Layered Inorganic–Organic Open Framework Material as a 4 V Positive Electrode with High‐Rate Performance for K‐Ion Batteries
Sign Up to like & getrecommendations! Published in 2019 at "Advanced Energy Materials"
DOI: 10.1002/aenm.201902528
Abstract: K‐ion batteries (KIBs) are promising for large‐scale energy storage owing to various advantages like the high abundance of potassium resources in the Earth's crust, high operational potentials, and high power due to fast diffusion of… read more here.
Keywords: capacity; rate; framework material; ion batteries ... See more keywords
Open Framework Material Based Thin Films: Electrochemical Catalysis and State‐of‐the‐art Technologies
Sign Up to like & getrecommendations! Published in 2021 at "Advanced Energy Materials"
DOI: 10.1002/aenm.202003499
Abstract: Open framework materials (OFMs), such as metal‐organic frameworks and covalent organic frameworks have emerged as promising electrocatalysts to address the global energy crisis and environmental problems. Powdered non‐film forms, that is, bulk OFMs exhibit excellent… read more here.
Keywords: material based; based thin; thin films; framework material ... See more keywords
Ultrafast-kinetics, ultralong-cycle-life, bifunctional inorganic open-framework for potassium-ion batteries
Sign Up to like & getrecommendations! Published in 2021 at "Energy Storage Materials"
DOI: 10.1016/j.ensm.2021.08.029
Abstract: Abstract Sluggish solid-state K+-migration kinetics and electrode material degradation represent two critical issues facing K-ion batteries. Here we report a new inorganic-open-framework (IOF) compound K0.76V0.55Nb0.45OPO4 (KVNP, synthesized through aliovalent substitution) which, as a bifunctional electrode… read more here.
Keywords: open framework; inorganic open; ion; ion batteries ... See more keywords
Two different types of channels exhibiting distinct proton transport behavior in an open-framework aluminophosphate
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2017.11.041
Abstract: Abstract A three-dimensional open-framework aluminophosphate, (NH4)2Al4(PO4)4(HPO4)·H2O (1), shows two types of eight-membered polyhedral ring channels. The lattice water molecules occupy within the channel with (HO)PO3 tetrahedra (channel-I), whilst the ammonium ions reside in another type… read more here.
Keywords: open framework; proton; conductivity; framework aluminophosphate ... See more keywords
On-Demand Atomic Hydrogen Provision by Exposing Electron-Rich Cobalt Sites in an Open-Framework Structure toward Superior Electrocatalytic Nitrate Conversion to Dinitrogen.
Sign Up to like & getrecommendations! Published in 2021 at "Environmental science & technology"
DOI: 10.1021/acs.est.1c06091
Abstract: Electrocatalytic nitrate (NO3-) reduction to N2 via atomic hydrogen (H*) is a promising approach for advanced water treatment. However, the reduction rate and N2 selectivity are hindered by slow mass transfer and H* provision-utilization mismatch,… read more here.
Keywords: provision; electrocatalytic nitrate; atomic hydrogen; nitrate ... See more keywords
Studies on the Genesis and Proton Conductivity of Imidazole-Based Linear and Open-Framework Zinc Phosphites.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00372
Abstract: Three new zinc phosphites, [HIm]2[Zn3(HPO3)4] (1), [Zn2(HPO3)2Im2] (2), and [Zn(HPO3)Im] (3) (Im = imidazole), have been synthesized from the hydro/solvothermal reaction of zinc acetate, dimethyl phosphite, and imidazole by varying the temperature and solvent of… read more here.
Keywords: studies genesis; open framework; zinc; hpo3 ... See more keywords
Open-Framework Iron Fluoride Phosphates Based on Chain, Trinuclear, and Tetranuclear Chain FeIII Building Units: Crystal Structures and Magnetic Properties.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00997
Abstract: We report the synthesis and characterization of a series of new open-framework iron fluoride-fluorophosphates based on linear, trinuclear, and tetranuclear chain FeIII building units. KFe2(PO3F)2F3 (I) consists of {Fe2(O3F)2F2}10- zigzag chains interconnected by P(O/F)4 tetrahedra… read more here.
Keywords: framework iron; chain; iron fluoride; framework ... See more keywords
Open-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties.
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DOI: 10.1021/acs.inorgchem.7b01423
Abstract: Two borophosphates, (NH4)1-2xM1+x(H2O)2(BP2O8)·yH2O with M = Mn (I) and Co (II), synthesized hydrothermally crystallize in enantiomorphous space groups P6522 and P6122 with a = 9.6559(3) and 9.501(3) Å, c = 15.7939(6) and 15.582(4) Å, and… read more here.
Keywords: open framework; helical chains; framework manganese; mn2 co2 ... See more keywords
Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00101
Abstract: Three zeolitic pentaborates (H2en)[B5O8(OH)] (1, en = ethylenediamine), (Hen)2[Al(B5O10)] (2), (H2en)[NH(CH3)2][Al(B5O10)] (3) were solvothermally obtained by employing ethanediamine molecules as structure-directing agents (SDAs). The nonmetal borate of 1 features a noncentrosymmetric two-dimensional layered structure. Through… read more here.
Keywords: open framework; framework; zeolitic open; topology ... See more keywords
An Open-Framework Structured Material: [Ni(en)2]3[Fe(CN)6]2 as a Cathode Material for Aqueous Sodium- and Potassium-Ion Batteries.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c00143
Abstract: Open-framework structured materials such as Prussian blue analogues and sodium superionic conductor (NASICON) materials have been regarded as promising electrode candidates for aqueous batteries. These materials exhibit outstanding long cycle stability and high rate capacity… read more here.
Keywords: ion batteries; material; ion; framework structured ... See more keywords