Iridium-Catalyzed Enantioselective Ring Opening of Alkenyl Oxiranes by Unactivated Carboxylic Acids.
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DOI: 10.1021/acs.orglett.2c02919
Abstract: An iridium-catalyzed enantioselective ring-opening of alkenyl oxiranes by unactivated carboxylic acids has been developed. The reaction undergoes at ambient conditions between an in-situ-generated chiral iridium-π-allyl complex and carboxylic acids to provide rapid access to valuable… read more here.
Keywords: opening alkenyl; iridium catalyzed; catalyzed enantioselective; enantioselective ring ... See more keywords