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Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c00390
Abstract: The copper-catalyzed reaction of arylcyclopropanes, N-fluorobis(arenesulfonyl)imides, and (bpy)Zn(CF3)2 (bpy = 2,2'-bipyridine) at room temperature affords the corresponding ring-opening 1,3-aminotrifluoromethylation products in satisfactory yields. The protocol is highly regioselective, providing a convenient entry to γ-trifluoromethylated amines.…
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Keywords:
ring opening;
aminotrifluoromethylation arylcyclopropanes;
opening aminotrifluoromethylation;
catalyzed ring ... See more keywords