Recent Advances in Ring-Opening Functionalization of Cycloalkanols by C-C σ-Bond Cleavage.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical record"
DOI: 10.1002/tcr.201700090
Abstract: Cycloalkanols prove to be privileged precursors for the synthesis of distally substituted alkyl ketones and polycyclic aromatic hydrocarbons (PAHs) by virtue of cleavage of their cyclic C-C bonds. Direct functionalization of cyclobutanols to build up… read more here.
Keywords: ring opening; cleavage; opening functionalization; recent advances ... See more keywords
Biopatterned Reorganization of Alkaloids Enabled by Ring-Opening Functionalization of Tertiary Amines.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c10205
Abstract: Biosynthetic processes often involve reorganization of one family of natural products to another. Chemical emulation of nature's rearrangement-based structural diversification strategy would enable the conversion of readily available natural products to other value-added secondary metabolites.… read more here.
Keywords: ring opening; natural products; opening functionalization; reorganization ... See more keywords
Silylium ion-mediated cage-opening functionalization of closo-B10H102- salts.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04892b
Abstract: The cage-opening functionalization of stable closo-B10H102- salts is a great way to get various boron clusters. However, the known methods to mediate cage-opening functionalization rely on the use of strong acids, which suffer from low… read more here.
Keywords: cage opening; b10h102 salts; cage; closo b10h102 ... See more keywords