Iron-Catalyzed Reductive Ring Opening/gem-Difluoroallylation of Cyclopropyl Ketones.
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DOI: 10.1021/acs.orglett.3c00398
Abstract: By merging C-C and C-F bond cleavage, we developed a regioselective ring opening/gem-difluoroallylation of cyclopropyl ketones with α-trifluoromethylstyrenes, which proceeds under the catalysis of iron with the combination of manganese and TMSCl as the reducing… read more here.
Keywords: gem; gem difluoroallylation; cyclopropyl ketones; opening gem ... See more keywords