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   Articles with "orbital hybridization" as a keyword



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p-d Orbital Hybridization Induced by p-Block Metal-Doped Cu Promotes the Formation of C2+ Products in Ampere-Level CO2 Electroreduction.

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recommendations! Published in 2023 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c12743

Abstract: Large-current electrolysis of CO2 to multi-carbon (C2+) products is critical to realize the industrial application of CO2 conversion. However, the poor binding strength of *CO intermediates on the catalyst surface induces multiple competing pathways, which… read more here.

Keywords: hybridization; orbital hybridization; metal doped; block metal ... See more keywords
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d-sp orbital hybridization: a strategy for activity improvement of transition metal catalysts.

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recommendations! Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc02299k

Abstract: Orbital hybridization to regulate the electronic structures and surface chemisorption properties of transition metals has been extensively investigated for searching high-performance catalysts toward various reactions. Unlike conventional d-d hybridization, the d-sp hybridization interaction between transition… read more here.

Keywords: hybridization; orbital hybridization; metal catalysts; transition metal ... See more keywords
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Orbital Hybridization and Hypersensitivity of Eu3+ in YXO4 (X=P, As, V)

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recommendations! Published in 2023 at "ECS Journal of Solid State Science and Technology"

DOI: 10.1149/2162-8777/acd80f

Abstract: A comparative study of Eu3+ ion luminescence in YXO4 (X=P, As, V) with the tetragonal zircon structure is conducted in relation to the intensity of the hypersensitivity 5D07F2 (∆J=2) transition. Both the asymmetry ratio, R=(I(5_(D_0… read more here.

Keywords: 5d0 7f2; 7f2 transition; hybridization; orbital hybridization ... See more keywords
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Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals

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recommendations! Published in 2020 at "Molecules"

DOI: 10.3390/molecules25143113

Abstract: The combination of atomic orbitals to form hybrid orbitals of special symmetries can be related to the individual orbital polynomials. Using this approach, 8-orbital cubic hybridization can be shown to be sp3d3f requiring an f… read more here.

Keywords: hybridization coordination; atomic orbital; orbital hybridization; systematics ... See more keywords