Origin of the High‐Rate Energy Storage for Vacancy‐Rich Chalcogenides: Reinforced d‐p Orbital Hybridization Induced by Strain Field
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202508406
Abstract: The atomic‐level structure manipulation toward transition metal chalcogenides (TMCs) is a promising route to promote the kinetics and rate capability in hybrid supercapacitors (HSCs). Nevertheless, the mechanism of such a strategy remains ambiguous, which inhibits… read more here.
Keywords: mathrm; high rate; orbital hybridization; mathrm mathrm ... See more keywords
d‐p Orbital Hybridization Tailoring for Boosted Redox Kinetics in Li‐CO2 Batteries
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DOI: 10.1002/adfm.202514223
Abstract: Lithium‐carbon dioxide (Li‐CO2) batteries hold great promise for carbon neutrality but suffer from sluggish CO2 reduction (CO2RR) and evolution (CO2ER) kinetics, leading to high overpotentials and limited cycling stability. Transition metal chalcogenides are potential cathode… read more here.
Keywords: co2 batteries; hybridization tailoring; co2; orbital hybridization ... See more keywords
Engineering Orbital Hybridization in Advanced Electrocatalysts for Energy Conversion: Fundamentals, Modulations, and Perspectives
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DOI: 10.1002/aenm.202501129
Abstract: Catalytic coordinates are essentially the dynamic interactions of frontier orbitals when interacting with electrocatalysts and adsorbates under optimal reaction conditions. Flexible modifications in orbital hybridization enable intrinsic control over both the thermodynamics and kinetics of… read more here.
Keywords: energy; orbital hybridization; hybridization advanced; theory ... See more keywords
Asymmetric‐Orbital‐Hybridization Induced Electron Redistribution Enabling Stable Sodium Layered Oxides
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DOI: 10.1002/aenm.202504261
Abstract: Layered transition metal (TM) oxides have garnered great attention as viable cathodes for sodium‐ion batteries (SIBs), but the challenges of complicated multiphase transitions, severe structural deterioration and unstable oxygen redox reaction still hamper their practical… read more here.
Keywords: oxygen redox; electron redistribution; orbital hybridization; oxygen ... See more keywords
f-p-d Orbital Hybridization Promotes Hydroxyl Intermediate Adsorption for Electrochemical Biomolecular Oxidation and Identification.
Sign Up to like & getrecommendations! Published in 2025 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.4c05534
Abstract: The rational design of efficient hydroxyl intermediate (*OH) adsorption catalysts for dopamine electrooxidation still faces a major challenge. To address this challenge, a CeO2-loaded CuO catalyst inspired by the f-p-d orbital hybridization strategy is designed… read more here.
Keywords: hydroxyl intermediate; adsorption; orbital hybridization; oxidation ... See more keywords
Optimizing p-d Orbital Hybridization of High-Entropy Nanozymes Achieving Sensitive Point-of-Care Detection of Gastric Cancer Biomarkers.
Sign Up to like & getrecommendations! Published in 2025 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.5c06028
Abstract: Optimization of p-d orbital hybridization enhances charge interactions through increased orbital overlap, reduced electron transfer energy barriers, and regulated reaction activation energies, thereby significantly improving the catalytic kinetics. To implement the strategy, atomic substitution of… read more here.
Keywords: orbital hybridization; gastric cancer; entropy nanozymes; hybridization ... See more keywords
Crystalline/Amorphous Interface Engineering and d-sp Orbital Hybridization Synergistically Boosting the Electrocatalytic Performance of PdCu Bimetallene toward Formic Acid-Assisted Overall Water Splitting.
Sign Up to like & getrecommendations! Published in 2024 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.4c14531
Abstract: Advanced electrocatalysts capable of bifunctional catalysis for formic acid oxidation (FAOR) and hydrogen evolution reaction (HER) have garnered significant attention due to their exceptional energy efficiency. In this research, we have meticulously designed a PdCu… read more here.
Keywords: pdcu; formic acid; orbital hybridization; pdcu bimetallene ... See more keywords
Charge Redistribution via d-p Hybridization in NiCoP Supported on Ni5P4 Boosts Alkaline Hydrogen Production.
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DOI: 10.1021/acsami.5c07985
Abstract: Transition-metal phosphides (TMPs) are promising electrocatalysts for the hydrogen evolution reaction (HER), but their industrial-scale application is limited by sluggish water dissociation kinetics and insufficient active site exposure under alkaline conditions. Herein, we demonstrate orbital… read more here.
Keywords: redistribution; orbital hybridization; hydrogen production; hydrogen ... See more keywords
Oxygen Evolution Reaction of Amorphous/Crystalline Composites of NiFe(OH)x/NiFe2O4.
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DOI: 10.1021/acsnano.4c18951
Abstract: Orbital structures are strongly correlated with catalytic performance, whereas their regulation strategy is still in pursuit. Herein, the Fe 3d and O 2p orbital hybridization was optimized by controlling the content of amorphous NiFe(OH)x (a-NiFe(OH)x),… read more here.
Keywords: evolution reaction; orbital hybridization; crystalline; oxygen evolution ... See more keywords
p-d Orbital Hybridization Induced by p-Block Metal-Doped Cu Promotes the Formation of C2+ Products in Ampere-Level CO2 Electroreduction.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12743
Abstract: Large-current electrolysis of CO2 to multi-carbon (C2+) products is critical to realize the industrial application of CO2 conversion. However, the poor binding strength of *CO intermediates on the catalyst surface induces multiple competing pathways, which… read more here.
Keywords: hybridization; orbital hybridization; metal doped; block metal ... See more keywords
d-sp orbital hybridization: a strategy for activity improvement of transition metal catalysts.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02299k
Abstract: Orbital hybridization to regulate the electronic structures and surface chemisorption properties of transition metals has been extensively investigated for searching high-performance catalysts toward various reactions. Unlike conventional d-d hybridization, the d-sp hybridization interaction between transition… read more here.
Keywords: hybridization; orbital hybridization; metal catalysts; transition metal ... See more keywords