Assessing the 4f Orbital Participation in the Ln-C Bonds of [Li(THF)4][Ln(C6Cl5)4] (Ln = La, Ce).
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DOI: 10.1021/acs.inorgchem.2c02304
Abstract: The reaction of [Ln(NO3)3(THF)4] (Ln = La, Ce) with 4 equiv of LiC6Cl5 in Et2O resulted in the formation of the homoleptic lanthanide-aryl "ate" complexes [Li(THF)4][La(C6Cl5)4] ([Li][1]) and [Li(THF)4][Ce(C6Cl5)4] ([Li][2]). These complexes represent the first… read more here.
Keywords: assessing orbital; thf c6cl5; participation bonds; orbital participation ... See more keywords
Evaluating f-Orbital Participation in the UV═E Multiple Bonds of [U(E)(NR2)3] (E = O, NSiMe3, NAd; R = SiMe3).
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DOI: 10.1021/acs.inorgchem.3c00455
Abstract: The reaction of 1 equiv of 1-azidoadamantane with [UIII(NR2)3] (R = SiMe3) in Et2O results in the formation of [UV(NR2)3(NAd)] (1, Ad = 1-adamantyl) in good yields. The electronic structure of 1, as well as… read more here.
Keywords: spectroscopy; orbital participation; electronic structure; sime3 ... See more keywords