Determination of d-Orbital Populations in a Cobalt(II) Single-Molecule Magnet Using Single-Crystal X-ray Diffraction.
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DOI: 10.1021/acs.inorgchem.8b00513
Abstract: The tetrahedral cobalt(II) compound (Ph4P)2[Co(SPh)4] was the first mononuclear transition-metal complex shown to exhibit slow relaxation of the magnetization in zero external magnetic field. Because the relative populations of the d orbitals play a vital… read more here.
Keywords: crystal ray; orbital populations; single crystal; ray diffraction ... See more keywords