Metal-Organic Architectures Assembled from Multifunctional Polycarboxylates: Hydrothermal Self-Assembly, Structures, and Catalytic Activity in Alkane Oxidation.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02926
Abstract: A three-component aqueous reaction system comprising copper(II) acetate (metal node), poly(carboxylic acid) with a phenylpyridine or biphenyl core (main building block), and 1,10-phenanthroline (crystallization mediator) was investigated under hydrothermal conditions. As a result, four new… read more here.
Keywords: oxidation; organic architectures; metal organic; phen ... See more keywords
Trefoiled Propeller-Shaped Spiral Terpyridyl Metal-Organic Architectures.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01701
Abstract: Constructing exquisite and intricate molecular architectures is always the pursuit of chemists. In this report, the propeller-shaped trefoil structures S1 and S2 were successfully prepared by the stepwise self-assembly of predesigned tripodal metal-organic ligands, which… read more here.
Keywords: organic architectures; propeller shaped; metal organic; metal ... See more keywords
Biomimetic Self-Assembling Metal-Organic Architectures with Non-Iridescent Structural Coloration for Synergetic Antibacterial and Osteogenic Activity of Implants.
Sign Up to like & getrecommendations! Published in 2022 at "ACS nano"
DOI: 10.1021/acsnano.2c06030
Abstract: Materials in nature feature versatile and programmable interactions to render macroscopic architectures with multiscale structural arrangements. By rationally combining metal-carboxylate and metal-organophosphate coordination interactions, Au25(MHA)18 (MHA, 6-mercaptohexanoic acid) nanocluster self-assembled structural color coating films and… read more here.
Keywords: organic architectures; coordination; metal organic; activity ... See more keywords
Self-Assembly of Anionic Polyoxometalate-Organic Architectures Based on Lacunary Phosphomolybdates and Pyridyl Ligands.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b02541
Abstract: The development of novel systems for metal-organic architectures is an attractive research field because they are fascinating materials with unexplored functions. Lacunary polyoxometalates (POMs) offer structurally well-defined coordination sites with various coordination directions and numbers… read more here.
Keywords: self assembly; organic architectures; pyridyl ligands; anionic polyoxometalate ... See more keywords