P–C, P–N, and M–N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three- to Five-Membered Phosphametallacycles
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02720
Abstract: Reactions of the heterometallic MoRe complex [MoReCp(μ-PR*)(CO)6] and its MoMn analogue with some small molecules having N–N multiple bonds, such as diazoalkanes and organic azides, were investigated (R* = 2,4,6-C6H2tBu3). Reactions with excess ethyl diazoacetate… read more here.
Keywords: coordination; diazoalkanes organic; reactions heterometallic; organic azides ... See more keywords
Iron-Catalyzed Asymmetric Haloazidation of α,β-Unsaturated Ketones: Construction of Organic Azides with Two Vicinal Stereocenters.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b06029
Abstract: Organic azides play important roles in synthetic chemistry, chemical biology, drug discovery, and material science. Azido-functionalization of alkenes is one of the most efficient procedures for rapid introduction of azide group into organic compounds. But… read more here.
Keywords: catalyzed asymmetric; unsaturated ketones; iron catalyzed; organic azides ... See more keywords
Reactions of In-Zn bonds with organic azides: products that result from hetero- and homo-bimetallic behaviour.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03990b
Abstract: The indyl anion, K[In(NONDipp)] (NONDipp = [O(SiMe2NDipp)2]2-, Dipp = 2,6-iPr2C6H3) reacts with group 12 compounds M(BDIR)Cl (M = Zn, Cd; BDI = [HC{C(Me)NR}2]-, R = 2,4,6-Me3C6H2 (Mes), Dipp) to afford the heterobimetallic compounds (NONDipp)In-M(BDIR) that… read more here.
Keywords: products result; result hetero; reactions bonds; organic azides ... See more keywords
Convenient synthesis of spiroindolenines from tryptamine-derived isocyanides and organic azides by cobalt catalysis in pure water
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DOI: 10.1039/d1gc00270h
Abstract: A Co-catalyzed coupling of 3-(2-isocyanoethyl)indoles with organic azides in pure water for accessing spiroindolenine derivatives was developed. This strategy features mild reaction conditions, high atom-economy, excellent yields, wide substrate scopes, and broad functional group tolerance.… read more here.
Keywords: pure water; organic azides; synthesis spiroindolenines; convenient synthesis ... See more keywords
Access to quinolinones via DMAP-catalysed cascade reaction of 2-substituted benzoic acids with organic azides.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04406d
Abstract: Herein, we report a DMAP-catalysed Curtius rearrangement and intramolecular cyclisation cascade reaction of 2-substituted aryl carboxylic acids with organic azides for the first time. This protocol features simple operation, broad scope and metal-free conditions, furnishing… read more here.
Keywords: acids organic; reaction substituted; reaction; dmap catalysed ... See more keywords
Electrochemical Studies of the Cycloaddition Activity of Bismuth(III) Acetylides Towards Organic Azides Under Copper(I)-Catalyzed Conditions
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.830237
Abstract: Time-dependent monitoring of the reactive intermediates provides valuable information about the mechanism of a synthetic transformation. However, the process frequently involves intermediates with short lifetimes that significantly challenge the accessibility of the desired kinetic data.… read more here.
Keywords: iii acetylides; copper catalyzed; bismuth iii; organic azides ... See more keywords