l-lactide polymerization – living and controlled – catalyzed by initiators: Hydroxyalkylated organic bases
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DOI: 10.1016/j.polymer.2016.11.070
Abstract: Abstract Polymerizations of l -lactide (LA) were initiated with hydroxyalkylated strong organic bases functioning simultaneously as catalysts (INICATs). Organocatalysts used until now in Ring-Opening Polymerization, particularly of l -lactide, had to be combined with separately… read more here.
Keywords: organic bases; lactide polymerization; polymerization; polymerization living ... See more keywords
The influence of organic bases and substituted groups on coordination structures affording two mononuclear Dy(iii) single-molecule magnets (SMMs) and a novel Dy(iii)–K(i) compound with unusually coordinated fluorine atoms
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DOI: 10.1039/d1ce00431j
Abstract: The different organic bases and substituted groups of auxiliary ligands play an important role in synthetic processes, finally affording distinct structures and magnetic properties. read more here.
Keywords: influence organic; bases substituted; coordination structures; groups coordination ... See more keywords
CO2 atmosphere enables efficient catalytic hydration of ethylene oxide by ionic liquids/organic bases at low water/epoxide ratios
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DOI: 10.1039/d1gc00758k
Abstract: The development of an efficient and low-cost strategy for the production of monoethylene glycol (MEG) through hydration of ethylene oxide (EO) at low H2O/EO molar ratios is an important industrial challenge. We have established that… read more here.
Keywords: hydration ethylene; ethylene oxide; hydration; liquids organic ... See more keywords
Comparative Physicochemical and Catalytic Study of Nanocrystalline Mg-Al Hydrotalcites Precipitated with Inorganic and Organic Bases
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DOI: 10.3390/nano12162775
Abstract: Synthetic Mg-Al hydrotalcites (HT) are environmentally friendly solid bases frequently applied as catalysts in base catalyzed reactions. The most common synthesis method, using NaOH as precipitant, is problematized by the possibility of introducing undesired Na… read more here.
Keywords: study nanocrystalline; comparative physicochemical; organic bases; physicochemical catalytic ... See more keywords