A chiral, porous, organic cage-based, enantioselective potentiometric sensor for 2-aminobutanol.
Sign Up to like & getrecommendations! Published in 2017 at "Chirality"
DOI: 10.1002/chir.22684
Abstract: A new enantioselective potentiometric sensor containing R-type chiral porous organic cage CC9 as the chiral selector was designed for the assay of 2-aminobutanol. Optimized membrane electrodes displayed a linear dynamic range from 10-3 ~ 10-1 mol·L-1… read more here.
Keywords: enantioselective potentiometric; porous organic; organic cage; potentiometric sensor ... See more keywords
Toward the Controlled Synthesis of Highly Dispersed Metal Clusters Enabled by Downsizing Crystalline Porous Organic Cage Supports
Sign Up to like & getrecommendations! Published in 2022 at "Small Methods"
DOI: 10.1002/smtd.202200591
Abstract: The controlled synthesis of subnanometer‐sized metal clusters (MCs) presents a fascinating prospect for the research of size‐dependent properties. In this study, a facile approach by employing porous racemic organic cage crystals as supports for immobilizing… read more here.
Keywords: controlled synthesis; metal clusters; organic cage; cage ... See more keywords
An iridium(III)-palladium(II) metal-organic cage for efficient mitochondria-targeted photodynamic therapy
Sign Up to like & getrecommendations! Published in 2020 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2019.09.034
Abstract: Abstract An Ir8Pd4-heteronuclear metal-organic cage (MOC-51) was assembled from bipodal metalloligand [Ir(ppy)2(qpy)(BF4)] (qpy = 4,4′:2′,2″:4″,4‴-quaterpyridine; ppy = 2-phenylpridine) with Pd(II) salt. The cubic barrel shaped MOC shows one-photon and two-photon excited deep-red emission, as well as large singlet oxygen… read more here.
Keywords: mitochondria; organic cage; photodynamic therapy; metal organic ... See more keywords
Synthesis of porous organic cage CC3 via solvent modulated evaporation
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119312
Abstract: Abstract We demonstrate a Humidity Modulated Solvent Evaporation (HMSE) approach to promote the nucleation and growth of CC3 crystals. This approach relies on the gradual evaporation of dichloromethane (solvent) from a diluted concentration of CC3… read more here.
Keywords: organic cage; evaporation; porous organic; solvent ... See more keywords
SO2 Capture and Oxidation in a Pd6L8 Metal-Organic Cage.
Sign Up to like & getrecommendations! Published in 2021 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c00408
Abstract: The facile and green preparation of novel materials that capture sulfur dioxide (SO2) with significant uptake at room temperature remains challenging, but it is crucial for public health and the environment. Herein, we explored for… read more here.
Keywords: adsorption; organic cage; metal organic; metal ... See more keywords
Solvatomorphism Influence of Porous Organic Cage on C2H2/CO2 Separation.
Sign Up to like & getrecommendations! Published in 2021 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c04573
Abstract: Porous organic molecular (POM) materials can exhibit solvatomorphs via altering their crystallographic packing in the solid state, but investigating real gas mixture separation by porous materials with such a behavior is still very rare. Herein,… read more here.
Keywords: organic cage; cpoc 101; porous organic; c2h2 co2 ... See more keywords
Highly Emissive Organic Cage in Single-Molecule and Aggregate States by Anchoring Multiple Aggregation-Caused Quenching Dyes.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c17640
Abstract: It remains a great challenge to design and synthesize organic luminescent molecules with strong emission in both dilute solution and aggregate state. Herein, an organic cage with dodecadansyl groups (D-RCC1) from an easy sulfonation reaction… read more here.
Keywords: molecule aggregate; single molecule; aggregate states; cage ... See more keywords
Highly Ion-Permselective Porous Organic Cage Membranes with Hierarchical Channels.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00318
Abstract: Membranes of high ion permselectivity are significant for the separation of ion species at the subnanometer scale. Here, we report porous organic cage (i.e., CC3) membranes with hierarchical channels including discrete internal cavities and cage-aligned… read more here.
Keywords: cage; membranes hierarchical; hierarchical channels; ion ... See more keywords
Analogy Powered by Prediction and Structural Invariants: Computationally Led Discovery of a Mesoporous Hydrogen-Bonded Organic Cage Crystal
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02653
Abstract: Mesoporous molecular crystals have potential applications in separation and catalysis, but they are rare and hard to design because many weak interactions compete during crystallization, and most molecules have an energetic preference for close packing.… read more here.
Keywords: mesoporous hydrogen; prediction; structural invariants; organic cage ... See more keywords
Efficient ethylene purification by a robust ethane-trapping porous organic cage
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-24042-7
Abstract: The removal of ethane (C2H6) from its analogous ethylene (C2H4) is of paramount importance in the petrochemical industry, but highly challenging due to their similar physicochemical properties. The use of emerging porous organic cage (POC)… read more here.
Keywords: ethane; c2h6 c2h4; porous organic; organic cage ... See more keywords
A smart and responsive crystalline porous organic cage membrane with switchable pore apertures for graded molecular sieving
Sign Up to like & getrecommendations! Published in 2022 at "Nature Materials"
DOI: 10.1038/s41563-021-01168-z
Abstract: Membranes with high selectivity offer an attractive route to molecular separations, where technologies such as distillation and chromatography are energy intensive. However, it remains challenging to fine tune the structure and porosity in membranes, particularly… read more here.
Keywords: porous organic; membrane; organic cage; crystalline porous ... See more keywords