Sulfur Dioxide Capture in Metal-Organic Frameworks, Metal-Organic Cages, and Porous Organic Cages.
Sign Up to like & getrecommendations! Published in 2022 at "ChemPlusChem"
DOI: 10.1002/cplu.202200006
Abstract: Capture, storage and subsequent controlled release or transformation of sulfur dioxide (SO2 ) in mild conditions is still a challenge in the material science field. Recent advances in the use of porous materials have demonstrated… read more here.
Keywords: sulfur dioxide; organic frameworks; organic cages; metal organic ... See more keywords
Strategies for the Construction of Functional Materials Utilizing Presynthesized Metal-Organic Cages (MOCs).
Sign Up to like & getrecommendations! Published in 2022 at "ChemPlusChem"
DOI: 10.1002/cplu.202200172
Abstract: Metal-organic cages (MOCs) that assemble from metal ions or metal clusters and organic ligands have attracted the interest of the scientific community because of their various functional coordination cavities. Unlike metal-organic frameworks (MOFs) with infinite… read more here.
Keywords: organic cages; functional materials; metal organic; cages mocs ... See more keywords
Chiral metal–organic cages/containers (MOCs): From structural and stereochemical design to applications
Sign Up to like & getrecommendations! Published in 2019 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2017.10.031
Abstract: Abstract During the past few decades, great efforts have been devoted to the design and self-assembly of discrete metal–organic cages/containers (MOCs) with increasing complexity and functionality. Among which, the incorporation of chirality into the construction… read more here.
Keywords: cages containers; metal; chiral metal; metal organic ... See more keywords
Porous organic cages embedded in a lipid membrane for water desalination: A molecular simulation study
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Membrane Science"
DOI: 10.1016/j.memsci.2018.11.053
Abstract: Abstract We report a molecular simulation study on porous organic cages (POCs) embedded in a lipid membrane for water desalination by reverse osmosis (RO). Four types of POC channels are examined namely straight, tilted, tilted… read more here.
Keywords: water; simulation study; membrane; molecular simulation ... See more keywords
Porous Organic Cages
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Reviews"
DOI: 10.1021/acs.chemrev.2c00667
Abstract: Porous organic cages (POCs) are a relatively new class of low-density crystalline materials that have emerged as a versatile platform for investigating molecular recognition, gas storage and separation, and proton conduction, with potential applications in… read more here.
Keywords: porous organic; chemistry; organic cages;
Self-Assembly of Two Tubular Metalloligand-Based Palladium-Organic Cages as Hosts for Polycyclic Aromatic Hydrocarbons.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04505
Abstract: Herein we report two tubular metal-organic cages (MOCs), synthesized by the self-assembly of bidentate metalloligands with different lengths and PdII. These two MOCs feature Pd4L8-type square tubular and Pd3L6-type triangular cage structures, respectively. Both MOCs… read more here.
Keywords: aromatic hydrocarbons; self assembly; organic cages; polycyclic aromatic ... See more keywords
Side Group of Hydrophobic Amino Acids Controls Chiral Discrimination among Chiral Counterions and Metal-Organic Cages.
Sign Up to like & getrecommendations! Published in 2022 at "Nano letters"
DOI: 10.1021/acs.nanolett.2c00908
Abstract: The self-assembly of chiral Pd12L24 metal-organic cages (MOCs) based on hydrophobic amino acids, including alanine (Ala), valine (Val), and leucine (Leu), into single-layered hollow spherical blackberry-type structures is triggered by nitrates through counterion-mediated attraction. In… read more here.
Keywords: chiral discrimination; chiral counterions; organic cages; metal organic ... See more keywords
Enhanced Biological Imaging via Aggregation-Induced Emission Active Porous Organic Cages.
Sign Up to like & getrecommendations! Published in 2022 at "ACS nano"
DOI: 10.1021/acsnano.1c08605
Abstract: Porous organic cages (POCs) have many advantages, including superior microenvironments, good monodispersity, and shape homogeneity, excellent molecular solubility, high chemical stability, and intriguing host-guest chemistry. These properties enable POCs to overcome the limitations of extended… read more here.
Keywords: porous organic; induced emission; aggregation induced; aggregation ... See more keywords
Design Elements for Enhanced Hydrogen Isotope Separations in Barely Porous Organic Cages
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c07041
Abstract: Barely porous organic cages (POCs) successfully separate hydrogen isotopes (H2/D2) at temperatures below 100 K. Identifying the mechanisms that control the separation process is key to the design of next-generation hydrogen separation materials. Here, ab… read more here.
Keywords: porous organic; organic cages; hydrogen; design ... See more keywords
Fine-Tuning Apertures of Metal-Organic Cages: Encapsulation of Carbon Dioxide in Solution and Solid State.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b04520
Abstract: Metal-organic cages are potential artificial models for mimicking biological functions due to their capability of selective encapsulation for certain guest molecules. In this work, we designed and synthesized a series of rhombic dodecahedral Ni-imidazolate cages… read more here.
Keywords: solid state; fine tuning; metal organic; solution ... See more keywords
Porous organic cages as synthetic water channels
Sign Up to like & getrecommendations! Published in 2020 at "Nature Communications"
DOI: 10.1038/s41467-020-18639-7
Abstract: Nature has protein channels (e.g., aquaporins) that preferentially transport water molecules while rejecting even the smallest hydrated ions. Aspirations to create robust synthetic counterparts have led to the development of a few one-dimensional channels. However,… read more here.
Keywords: synthetic water; water; water channels; porous organic ... See more keywords