Modifying Enzymatic Substrate Binding within a Metal-Organic Capsule for Supramolecular Catalysis.
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DOI: 10.1021/jacs.3c00626
Abstract: Supramolecular catalysis is established to modify reaction kinetics by substrate encapsulation, but manipulating the thermodynamics of electron-transfer reactions remains unexplored. Herein, we reported a new microenvironment-shielding approach to induce an anodic shift in the redox… read more here.
Keywords: within metal; substrate binding; metal organic; substrate ... See more keywords