Fabrication of Metal–Organic Framework‐Derived LaCo/C‐Decorated Ti3C2Tx Composites with High Electromagnetic Wave Absorption
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DOI: 10.1002/adem.202302106
Abstract: Thin‐thickness and lightweight electromagnetic wave (EMW) absorption materials are critically needed for stealth technology in the military stealth field. The special structure of a material is important for improving its good EMW absorption. Herein, a… read more here.
Keywords: framework derived; organic framework; absorption; ti3c2tx ... See more keywords
Hydrogen‐Bonded Polyimide/Metal‐Organic Framework Hybrid Membranes for Ultrafast Separations of Multiple Gas Pairs
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DOI: 10.1002/adfm.201903243
Abstract: Membranes have seen a growing role in mitigating the extensive energy used for gas separations. Further expanding their effectiveness in reducing the energy penalty requires a fast separation process via a facile technique readily integrated… read more here.
Keywords: polyimide metal; membrane; hydrogen; metal organic ... See more keywords
The Art of Integrated Functionalization: Super Stable Black Phosphorus Achieved through Metal‐Organic Framework Coating
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DOI: 10.1002/adfm.202002232
Abstract: Black phosphorus (BP) is a promising 2D nanomaterial with a great potential in various areas, while its intrinsic instability greatly suppresses practical applications, particularly under harsh conditions (e.g., high temperature). Herein, BP functionalization with Al… read more here.
Keywords: integrated functionalization; functionalization; metal organic; black phosphorus ... See more keywords
A 3D Cu‐Naphthalene‐Phosphonate Metal–Organic Framework with Ultra‐High Electrical Conductivity
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DOI: 10.1002/adfm.202007294
Abstract: A conductive phosphonate metal–organic framework (MOF), [{Cu(H2O)}(2,6‐NDPA)0.5] (NDPA = naphthalenediphosphonic acid), which contains a 2D inorganic building unit (IBU) comprised of a continuous edge‐sharing sheet of copper phosphonate polyhedra is reported. The 2D IBUs are… read more here.
Keywords: conductivity; organic framework; metal organic; phosphonate metal ... See more keywords
Diverse Metal–Organic Framework Architectures for Electromagnetic Absorbers and Shielding
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DOI: 10.1002/adfm.202100470
Abstract: Metal–organic frameworks (MOFs) and their derivatives, featuring unique 3D microstructures and enhanced electromagnetic properties, are illuminating infinite possibilities for electromagnetic functional materials and devices, receiving significant attention from domestic and foreign researchers. Herein, the design… read more here.
Keywords: architectures electromagnetic; framework architectures; diverse metal; metal organic ... See more keywords
Manifestation of Strongly Correlated Electrons in a 2D Kagome Metal–Organic Framework
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DOI: 10.1002/adfm.202106474
Abstract: The kagome lattice, whose electronic valence band (VB) structure includes two Dirac bands and one flat band1–3, offers a rich space to realise tuneable topological and strongly correlated electronic phases1,4 in two-dimensional (2D) and layered… read more here.
Keywords: metal organic; metal; strongly correlated; manifestation strongly ... See more keywords
Multi‐Scale Design of Metal–Organic Framework Metamaterials for Broad‐Band Microwave Absorption
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DOI: 10.1002/adfm.202402923
Abstract: The development of nanocomposite microwave absorbers is a critical strategy for tackling electromagnetic pollution. However, challenges persist regarding material stability and achieving broadband absorption. Herein, a novel multi−scale design approach for metamaterial absorbers is proposed.… read more here.
Keywords: organic framework; multi scale; absorption; design ... See more keywords
Insights into a New Multi‐Stimuli‐Responsive Photochromic Metal‐Organic Framework: Highly Sensitive Turn‐On Luminescence in a Lanthanum Phosphonate
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DOI: 10.1002/adfm.202403631
Abstract: The new microporous metal organic framework [La2(H2O)5(H2TPPE)]·3H2O (CAU‐54), is obtained in a hydrothermal reaction of the linker 1,1,2,2‐tetrakis(4′‐phosphonophenyl)ethylene (H8TPPE) and La3+ ions. The extensive characterization including temperature‐dependent crystal structures and spectroscopic properties allowed to understand… read more here.
Keywords: temperature; organic framework; luminescence; metal organic ... See more keywords
Dual‐Wing Ligand Constructed Metal–Organic Framework Membranes with Finely Tuned Apertures for Natural Gas Separation
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DOI: 10.1002/adfm.202404681
Abstract: Metal–organic framework (MOF) membranes with apparent molecular sieving effects have great potential for gas separation. However, their application in light‐gas separation (e.g., CO2/CH4 and H2/CH4) remains challenging due to their enlarged pore structures under transmembrane… read more here.
Keywords: separation; ch4; organic framework; gas ... See more keywords
Robust π‐Conjugated Hydrogen‐Bonded Organic Framework Nanowires Enable Stable and Fast Potassium Storage
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DOI: 10.1002/adfm.202407452
Abstract: Organic cathodes are considered promising energy storage materials in potassium ion batteries (KIBs) due to their molecular flexibility, cost‐effectiveness, and sustainability. However, challenges such as high solubility and slow reaction kinetics hinder the development of… read more here.
Keywords: bonded organic; organic framework; hydrogen bonded; storage ... See more keywords
Covalent–Organic‐Framework Membrane with Aligned Dipole Moieties for Biomimetic Regulable Ion Transport
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DOI: 10.1002/adfm.202409356
Abstract: Biological ion channels are renowned for their exceptional ion transport selectivity and adaptability to environmental changes, posing a significant challenge for synthetic mimicry. Herein, an innovative covalent–organic‐framework membrane featuring aligned benzothiadiazole units within its oriented… read more here.
Keywords: ion transport; organic framework; covalent organic; ion ... See more keywords