Multibranched Octupolar Module Embedded Covalent Organic Frameworks Enable Efficient Two‐Photon Fluorescence
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DOI: 10.1002/adfm.202000516
Abstract: Covalent organic frameworks (COFs) have emerged as potential light emitting polymers for optoelectronic and optical devices, but their nonlinear optical properties, particularly two‐photon absorption and fluorescence (TPA/TPF), have seldom been explored. Herein, to construct octupolar… read more here.
Keywords: two photon; photon fluorescence; covalent organic; organic frameworks ... See more keywords
Carbon Dots Based Nanoscale Covalent Organic Frameworks for Photodynamic Therapy
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DOI: 10.1002/adfm.202004680
Abstract: Covalent organic frameworks (COFs) have attracted much attention for various applications, while developing COFs with biomedical functions remains a big challenge. Most COFs are built purely from organic molecules, no carbon dots (CDs)‐based COFs have… read more here.
Keywords: photodynamic therapy; covalent organic; carbon dots; organic frameworks ... See more keywords
Mixed‐Valence Ce/Zr Metal‐Organic Frameworks: Controlling the Oxidation State of Cerium in One‐Pot Synthesis Approach
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DOI: 10.1002/adfm.202102582
Abstract: Authors acknowledge financial support by MINECO (Spain) through projects, MAT2017-86992-R and MAT2016-80285-P. EVRF acknowledges MINECO for his Ramon y Cajal fellow RYC-2012-11427. The authors also would like to thank Diamond Light Source (I20-Scanning beamline) for… read more here.
Keywords: metal organic; controlling oxidation; valence metal; mixed valence ... See more keywords
Metal‐Organic Frameworks Derived Titanium Oxides via Soft Interface Adaptive Transformation
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DOI: 10.1002/adfm.202107260
Abstract: High‐temperature treatment of metal‐organic frameworks (MOFs) is a promising route to prepare a variety of functional materials with diverse applications. However, it is challenging to prepare highly crystalline metal oxides such as TiO2 with controllable… read more here.
Keywords: interface; adaptive transformation; soft interface; metal organic ... See more keywords
Hydrogen‐Bonded Organic Frameworks as an Appealing Platform for Luminescent Sensing
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DOI: 10.1002/adfm.202403635
Abstract: Hydrogen‐bonded organic frameworks (HOFs), a novel subclass of porous crystalline materials self‐assembled from organic linkers through hydrogen bonding and other intermolecular interactions, have emerged as an exciting platform for developing multifunctional materials. Recently, luminescent HOF… read more here.
Keywords: bonded organic; organic frameworks; hydrogen bonded; luminescent ... See more keywords
Recent Progress and Challenge in Metal–Organic Frameworks for Lithium–Sulfur Battery Separators
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DOI: 10.1002/adfm.202405890
Abstract: The separators used in lithium‐sulfur (Li–S) batteries play a crucial role in their cycling performance and safety. Current commercial separators lack the ability to efficiently regulate polysulfide shuttling and are prone to thermal runaway at… read more here.
Keywords: battery; lithium sulfur; recent progress; organic frameworks ... See more keywords
Chemically Tailored Metal‐Organic Frameworks for Enhanced Capture of Short‐ and Long‐Chain Per‐ and Polyfluoroalkyl Substances from Water
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DOI: 10.1002/adfm.202409932
Abstract: Per‐ and polyfluoroalkyl substances (PFAS) are emerging as bioaccumulative and toxic water pollutants, posing a large threat to human and aquatic organisms. This threat is aggravated by their extreme persistence to common degradation methods. Adsorption… read more here.
Keywords: per polyfluoroalkyl; organic frameworks; short long; polyfluoroalkyl substances ... See more keywords
Metal–Organic Frameworks Photocatalyst Through Plasmon‐Induced Hot‐Electrons
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DOI: 10.1002/adfm.202410352
Abstract: Plasmonic metal–organic frameworks (plasmonic‐MOFs) ingeniously meld the homogeneous and vast porosity of MOFs with the distinctive plasmonic characteristics of metallic nanoparticles (NPs), creating a powerful synergy. This innovative combination is leveraged for enhanced plasmon‐induced hot‐electron… read more here.
Keywords: plasmon induced; induced hot; organic frameworks; frameworks photocatalyst ... See more keywords
Cradle‐to‐Gate Environmental Impact Assessment of Commercially Available Metal‐Organic Frameworks Manufacturing
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DOI: 10.1002/adfm.202410751
Abstract: Metal‐organic frameworks (MOFs) are promising next‐generation crystalline porous materials with exceptional structural, chemical, and application diversity. Since their discovery, the reticular tunability and physiochemical properties of MOFs have been studied and carefully manipulated to make… read more here.
Keywords: assessment; environmental impact; cradle gate; organic frameworks ... See more keywords
Inkjet Printed Metal–Organic Frameworks for Non‐Volatile Memory Devices Suitable for Printed RRAM
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DOI: 10.1002/adfm.202412372
Abstract: Inkjet printing has emerged as a promising technique for patterning functional materials, offering significant advantages over traditional subtractive thin‐film methods. Its versatility enables the structuring of various materials, expanding application ranges and minimizing waste through… read more here.
Keywords: inkjet; memory; inkjet printed; organic frameworks ... See more keywords
Linker Modulation of Covalent Organic Frameworks at Atomic Level for Enhanced and Selective Photocatalytic Oxidation of Thioether
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DOI: 10.1002/adfm.202413943
Abstract: Atomic‐level modulation of covalent organic frameworks (COFs) structure for enhanced photocatalytic oxidation is highly important but still challenging. Herein, a series of β‐ketoenamine‐linked COFs have been synthesized by using 2,4,6‐triformyl‐phloroglucinol (Tp) as a modular molecule,… read more here.
Keywords: modulation covalent; level; covalent organic; organic frameworks ... See more keywords