Polyoxometalate-based inorganic-organic hybrids based on a half rigid N-heterocyclic carboxylate ligand: Syntheses, structures and properties
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.128256
Abstract: Abstract Three new inorganic-organic hybrids constructed from a half rigid N-heterocyclic carboxylate ligand, K[Ag3(HL1)4](Mo8O26) (1), [Ag4(HL1)2(HL2)2(SiMo12O40)] (2) and (H3O)[Ag(L1)2]·2H2O (3) [HL1 = 1-(4-carboxylbenzyl)-3-(pyrazine-2-yl)pyrazole; HL2 = 3-(2-pyrazine)pyrazole], were hydrothermally synthesized and characterized. In compound 1, {K[β-Mo8O26]}n3n− chains fill in the… read more here.
Keywords: rigid heterocyclic; organic hybrids; carboxylate ligand; inorganic organic ... See more keywords
Synergetic Transformation of Solid Inorganic-Organic Hybrids into Advanced Nanomaterials for Catalytic Water Splitting.
Sign Up to like & getrecommendations! Published in 2018 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.8b00193
Abstract: The rational synthesis of advanced nanomaterials with well-defined structures has been intensively studied due to the remarkable properties and intriguing applications of the formed materials. Recently, inorganic-organic hybrids have been widely adopted as precursors for… read more here.
Keywords: organic hybrids; synergetic transformation; transformation; inorganic organic ... See more keywords
Highly Luminescent Inorganic-Organic Hybrids with Molecularly Dispersed Perylene.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00701
Abstract: A highly photoluminescent material was obtained by the incorporation of perylene into an inorganic-organic hybrid film. Octosilicate, a layered alkali silicate, was modified with a cationic surfactant, dioleyldimethylammonium ion, to accommodate perylene molecularly and uniformly.… read more here.
Keywords: hybrids molecularly; highly luminescent; organic hybrids; luminescent inorganic ... See more keywords
Two Unprecedented POM-Based Inorganic-Organic Hybrids with Concomitant Heteropolytungstate and Molybdate.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02601
Abstract: Two novel POM-based inorganic-organic hybrids, [Cu6II(2,2'-bipy)6(Mo6O22)(SiW12O40)]n (1), and {[Cu6II(ppz)6(H2O)5(MoO4)(SiW12O40)]·4H2O}n (2) (2,2'-bipy = 2,2'-bipyridine, Hppz = 3-(pyrid-2-yl)pyrazole), have been constructed from heteropolytungstates and molybdates. Two compounds have been identified by single crystal X-ray diffraction, elemental analysis,… read more here.
Keywords: two unprecedented; pom based; classical keggin; based inorganic ... See more keywords
From Ionic Nanoparticle Organic Hybrids to Ionic Nanocomposites: Structure, Dynamics, and Properties: A Review
Sign Up to like & getrecommendations! Published in 2022 at "Nanomaterials"
DOI: 10.3390/nano13010002
Abstract: Ionic nanoparticle organic hybrids have been the focus of research for almost 20 years, however the substitution of ionic canopy by an ionic-entangled polymer matrix was implemented only recently, and can lead to the formulation… read more here.
Keywords: ionic nanocomposites; nanoparticle; nanoparticle organic; chemistry ... See more keywords