A thiourea-functionalized metal-organic macrocycle for the catalysis of Michael additions and prominent size-selective effect.
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DOI: 10.1039/c6dt04299f
Abstract: A discrete tetranuclear thiourea-based metal-organic macrocycle (MOM) with a large size was constructed by a well-designed organic ligand and nickel(ii) ions via self-assembly. Incorporating thiourea groups as hydrogen-bond donors into a metal-organic complex system leads… read more here.
Keywords: organic macrocycle; size; metal organic; michael additions ... See more keywords