APPLICATION OF BF3•Et2O IN THE SYNTHESIS OF CYCLIC ORGANIC PEROXIDES
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/5956
Abstract: A summary of recent applications of Lewis acid BF3·Et2O as a catalyst in the synthesis of cyclic organic peroxides is presented. read more here.
Keywords: cyclic organic; organic peroxides; synthesis cyclic; bf3 et2o ... See more keywords
Application of BF3·Et2O in the synthesis of cyclic organic peroxides (microreview)
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-020-02785-3
Abstract: A summary of recent applications of Lewis acid BF3·Et2O as a catalyst in the synthesis of cyclic organic peroxides is presented. read more here.
Keywords: cyclic organic; organic peroxides; synthesis cyclic; bf3 et2o ... See more keywords
Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
Sign Up to like & getrecommendations! Published in 2018 at "Polymer Testing"
DOI: 10.1016/j.polymertesting.2018.03.014
Abstract: Abstract The efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly(e-caprolactone)/poly(3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function… read more here.
Keywords: mechanical thermal; phb blends; spectroscopy; pcl phb ... See more keywords
Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere.
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DOI: 10.1021/acs.chemrev.2c00430
Abstract: Organic peroxides (POs) are organic molecules with one or more peroxide (-O-O-) functional groups. POs are commonly regarded as chemically labile termination products from gas-phase radical chemistry and therefore serve as temporary reservoirs for oxidative… read more here.
Keywords: organic peroxides; reactive intermediates; key reactive; multiphase processes ... See more keywords
Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c01297
Abstract: Organic peroxides play a vital role in the formation, evolution, and health impacts of atmospheric aerosols, yet their molecular composition and fate in the particle phase remain poorly understood. Here, we identified, using iodometry-assisted liquid… read more here.
Keywords: isomer resolved; organic peroxides; organic aerosol; reactivity ... See more keywords
Organic Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate.
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DOI: 10.1021/acs.est.9b02591
Abstract: Sulfur oxides (SOx) are important atmospheric trace species in both gas and particulate phases, and sulfate is a major component of atmospheric aerosol. One potentially important source of particulate sulfate formation is the oxidation of… read more here.
Keywords: sulfate; particulate sulfate; source particulate; aerosol ... See more keywords
Reductive Cleavage of Organic Peroxides by Iron Salts and Thiols
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DOI: 10.1021/acsomega.8b01977
Abstract: Despite the low bond strength of the oxygen–oxygen bond, organic peroxides are often surprisingly resistant to cleavage by nucleophiles and reductants. As a result, achieving decomposition under mild conditions can be challenging. Herein, we explore… read more here.
Keywords: organic peroxides; reductive cleavage; iron salts; hindered peroxides ... See more keywords
Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides
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DOI: 10.3390/ma14154205
Abstract: Reactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic… read more here.
Keywords: pla blends; pla; pcl pla; mechanical properties ... See more keywords
Lewis Acids and Heteropoly Acids in the Synthesis of Organic Peroxides
Sign Up to like & getrecommendations! Published in 2022 at "Pharmaceuticals"
DOI: 10.3390/ph15040472
Abstract: Organic peroxides are an important class of compounds for organic synthesis, pharmacological chemistry, materials science, and the polymer industry. Here, for the first time, we summarize the main achievements in the synthesis of organic peroxides… read more here.
Keywords: acids synthesis; lewis acids; organic peroxides; synthesis organic ... See more keywords