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   Articles with "organic peroxides" as a keyword



APPLICATION OF BF3•Et2O IN THE SYNTHESIS OF CYCLIC ORGANIC PEROXIDES

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recommendations! Published in 2020 at "Chemistry of Heterocyclic Compounds"

DOI: 10.1007/5956

Abstract: A summary of recent applications of Lewis acid BF3·Et2O as a catalyst in the synthesis of cyclic organic peroxides is presented. read more here.

Keywords: cyclic organic; organic peroxides; synthesis cyclic; bf3 et2o ... See more keywords

Application of BF3·Et2O in the synthesis of cyclic organic peroxides (microreview)

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recommendations! Published in 2020 at "Chemistry of Heterocyclic Compounds"

DOI: 10.1007/s10593-020-02785-3

Abstract: A summary of recent applications of Lewis acid BF3·Et2O as a catalyst in the synthesis of cyclic organic peroxides is presented. read more here.

Keywords: cyclic organic; organic peroxides; synthesis cyclic; bf3 et2o ... See more keywords
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides

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recommendations! Published in 2018 at "Polymer Testing"

DOI: 10.1016/j.polymertesting.2018.03.014

Abstract: Abstract The efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly(e-caprolactone)/poly(3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function… read more here.

Keywords: mechanical thermal; phb blends; spectroscopy; pcl phb ... See more keywords

Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere.

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recommendations! Published in 2023 at "Chemical reviews"

DOI: 10.1021/acs.chemrev.2c00430

Abstract: Organic peroxides (POs) are organic molecules with one or more peroxide (-O-O-) functional groups. POs are commonly regarded as chemically labile termination products from gas-phase radical chemistry and therefore serve as temporary reservoirs for oxidative… read more here.

Keywords: organic peroxides; reactive intermediates; key reactive; multiphase processes ... See more keywords

Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol.

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recommendations! Published in 2022 at "Environmental science & technology"

DOI: 10.1021/acs.est.2c01297

Abstract: Organic peroxides play a vital role in the formation, evolution, and health impacts of atmospheric aerosols, yet their molecular composition and fate in the particle phase remain poorly understood. Here, we identified, using iodometry-assisted liquid… read more here.

Keywords: isomer resolved; organic peroxides; organic aerosol; reactivity ... See more keywords

Rapid Iron-Mediated Aqueous-Phase Reactions of Organic Peroxides from Monoterpene-Derived Criegee Intermediates and Implications for Aerosol and Cloud Chemistry.

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recommendations! Published in 2025 at "Environmental science & technology"

DOI: 10.1021/acs.est.4c08340

Abstract: Fenton-like reactions between organic peroxides and transition-metal ions in the atmospheric aqueous phase have profound impacts on the chemistry, composition, and health effects of aerosols. However, the kinetics, mechanisms, and key influencing factors of such… read more here.

Keywords: chemistry; fenton like; aqueous phase; organic peroxides ... See more keywords

Organic Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate.

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recommendations! Published in 2019 at "Environmental science & technology"

DOI: 10.1021/acs.est.9b02591

Abstract: Sulfur oxides (SOx) are important atmospheric trace species in both gas and particulate phases, and sulfate is a major component of atmospheric aerosol. One potentially important source of particulate sulfate formation is the oxidation of… read more here.

Keywords: sulfate; particulate sulfate; source particulate; aerosol ... See more keywords

Organic Peroxides in Transition-Metal-Free Cyclization and Coupling Reactions (C–C) via Oxidative Transformation

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recommendations! Published in 2025 at "ACS Omega"

DOI: 10.1021/acsomega.4c11574

Abstract: Transition-metal-free transformations are recognized as green and sustainable methods for constructing carbon–carbon bonds in organic synthesis. This review describes the application of six organic peroxides, including tert-butyl hydroperoxide (TBHP), di-tert-butyl peroxide (DTBP), tert-butyl peroxybenzoate (TBPB),… read more here.

Keywords: metal free; transition metal; coupling reactions; organic peroxides ... See more keywords
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Reductive Cleavage of Organic Peroxides by Iron Salts and Thiols

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recommendations! Published in 2018 at "ACS Omega"

DOI: 10.1021/acsomega.8b01977

Abstract: Despite the low bond strength of the oxygen–oxygen bond, organic peroxides are often surprisingly resistant to cleavage by nucleophiles and reductants. As a result, achieving decomposition under mild conditions can be challenging. Herein, we explore… read more here.

Keywords: organic peroxides; reductive cleavage; iron salts; hindered peroxides ... See more keywords

Water Microdroplets Surrounded by Alcohol Vapor Cause Spontaneous Oxidation of Alcohols to Organic Peroxides.

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recommendations! Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c04092

Abstract: Using real-time mass spectrometric (MS) monitoring, we demonstrate one-step, catalyst-free spontaneous oxidation of various alcohols (ROH) to key reactive intermediates for the formation of ROO- compounds on the surface of water microdroplets surrounded by alcohol… read more here.

Keywords: water; water microdroplets; organic peroxides; alcohol ... See more keywords
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Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides

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recommendations! Published in 2021 at "Materials"

DOI: 10.3390/ma14154205

Abstract: Reactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic… read more here.

Keywords: pla blends; pla; pcl pla; mechanical properties ... See more keywords