Modular Metal-Organic Polyhedra Superassembly: From Molecular-Level Design to Targeted Drug Delivery.
Sign Up to like & getrecommendations! Published in 2019 at "Advanced materials"
DOI: 10.1002/adma.201806774
Abstract: Targeted drug delivery remains at the forefront of biomedical research but remains a challenge to date. Herein, the first superassembly of nanosized metal-organic polyhedra (MOP) and their biomimetic coatings of lipid bilayers are described to… read more here.
Keywords: organic polyhedra; drug delivery; delivery; metal organic ... See more keywords
Facilitate Gas Transport through Metal-Organic Polyhedra Constructed Porous Liquid Membrane.
Sign Up to like & getrecommendations! Published in 2020 at "Small"
DOI: 10.1002/smll.201907016
Abstract: Type II porous liquids are demonstrated to be promise porous materials. However, the category of porous hosts is very limited. Here, a porous host metal-organic polyhedra (MOP-18) is reported to construct type II porous liquids.… read more here.
Keywords: organic polyhedra; porous liquid; porous liquids; metal organic ... See more keywords
Self-Assembly of Imidazolium-Functionalized Zr-Based Metal-Organic Polyhedra for Catalytic Conversion of CO2 into Cyclic Carbonates.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01199
Abstract: Three cationic capsule-shaped Zr-based metal-organic polyhedra (MOPs) with different cavity sizes were successfully constructed through the self-assembly of trinuclear zirconocene clusters and imidazolium-functionalized dicarboxylic ligands. Owing to the imidazolium groups in the MOPs, they show… read more here.
Keywords: organic polyhedra; self assembly; metal organic; co2 ... See more keywords
Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01780
Abstract: A series of multinuclear lanthanide-covalent organic polyhedra (LnCOPs), including pillar-typed triangular prisms 1-Ln3 and tetrahedra 2-Ln4 (Ln = LaIII, SmIII, EuIII), have been constructed for the first time, through either one-pot subcomponent self-assembly or postassembly… read more here.
Keywords: organic polyhedra; self assembly; lanthanide covalent; chameleonic luminescence ... See more keywords
Unusually Flexible Indium(III) Metal-Organic Polyhedra Materials for Detecting Trace Amounts of Water in Organic Solvents and High Proton Conductivity.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02963
Abstract: Humidity-induced single-crystal transformation was observed in the indium metal-organic polyhedra [In2(TCPB)2]·2H2O (In1), where H3TCPB is 1,3,5-tri(4-carboxyphenoxy)benzene. When the humidity is above 58% relative humidity (RH) at room temperature, the neutral compound In1 could be successfully… read more here.
Keywords: in1; organic polyhedra; proton conductivity; metal organic ... See more keywords
Three Sequential Hydrolysis Products of the Ubiquitous Cu24 Isophthalate Metal-Organic Polyhedra.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00997
Abstract: Metal-organic polyhedra (MOPs) are increasingly studied as host-guest capsules, linked into networks, or incorporated into composite materials. As such, understanding the decomposition of MOP structures is of fundamental importance. The degradation of the ubiquitous copper(II)… read more here.
Keywords: cu24; organic polyhedra; metal organic; isophthalate ... See more keywords
Metal-Organic Polyhedra-Coated Si Nanowires for the Sensitive Detection of Trace Explosives.
Sign Up to like & getrecommendations! Published in 2017 at "Nano letters"
DOI: 10.1021/acs.nanolett.6b02360
Abstract: Surface-modified silicon nanowire-based field-effect transistors (SiNW-FETs) have proven to be a promising platform for molecular recognition in miniature sensors. In this work, we present a novel nanoFET device for the sensitive and selective detection of… read more here.
Keywords: polyhedra coated; detection; organic polyhedra; metal organic ... See more keywords
Ammonia Capture in Rhodium(II)-Based Metal–Organic Polyhedra via Synergistic Coordinative and H-Bonding Interactions
Sign Up to like & getrecommendations! Published in 2023 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.2c19206
Abstract: Ammonia (NH3) is among the world’s most widely produced bulk chemicals, given its extensive use in diverse sectors such as agriculture; however, it poses environmental and health risks at low concentrations. Therefore, there is a… read more here.
Keywords: rhodium based; organic polyhedra; bdc; metal organic ... See more keywords
Automated Rational Design of Metal–Organic Polyhedra
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c03402
Abstract: Metal–organic polyhedra (MOPs) are hybrid organic–inorganic nanomolecules, whose rational design depends on harmonious consideration of chemical complementarity and spatial compatibility between two or more types of chemical building units (CBUs). In this work, we apply… read more here.
Keywords: organic polyhedra; rational design; metal organic;
Reversible Discrete-to-Extended Metal-Organic Polyhedra Transformation by Sulfonic Acid Surface Functionalization.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07978
Abstract: Metal-organic polyhedra (MOPs) are molecular porous units in which desired functionalities can be installed with precise geometrical and compositional control. By combing two complementary chemical moieties, such as sulfonic acid groups and Rh(II)-carboxylate paddlewheel, we… read more here.
Keywords: sulfonic acid; organic polyhedra; transformation; metal organic ... See more keywords
Homochiral Porous Metal-Organic Polyhedra with Multiple Kinds of Vertices.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12424
Abstract: Metal-organic polyhedra featuring non-Archimedean/Platonic architectures with multiple kinds of vertices have aroused great attention for their fascinating structures and properties but are yet challenging to achieve. Here, we report a combinatorial strategy to make such… read more here.
Keywords: multiple kinds; kinds vertices; metal organic; organic polyhedra ... See more keywords