Controllable photomechanical bending of metal-organic rotaxane crystals facilitated by regioselective confined-space photodimerization
Sign Up to like & getrecommendations! Published in 2022 at "Nature Communications"
DOI: 10.1038/s41467-022-29738-y
Abstract: Molecular machines based on mechanically-interlocked molecules (MIMs) such as (pseudo) rotaxanes or catenates are known for their molecular-level dynamics, but promoting macro-mechanical response of these molecular machines or related materials is still challenging. Herein, by… read more here.
Keywords: photodimerization; organic rotaxane; rotaxane; metal organic ... See more keywords
Syntheses of cucurbit[6]uril-based metal-organic rotaxane networks by the anion regulation strategy and their proton conduction properties.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04172a
Abstract: Two new cucurbit[6]uril (CB[6])-based metal-organic rotaxane networks (MORNs) were successfully obtained by tuning the coordination sphere of metal copper clusters. Compounds 1 and 2 exhibited relatively high proton conductivity at 85 °C and 97% relative… read more here.
Keywords: uril based; cucurbit uril; metal organic; based metal ... See more keywords
Three layered cucurbit[6]uril-based metal-organic rotaxane networks functionalized by sulfonic groups for proton conduction.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01283a
Abstract: Three new cucurbit[6]uril (CB[6])-based metal-organic rotaxane networks (MORNs) (named CUST-711, CUST-712, and CUST-713) functionalized by a sulfonic group (-SO3H) have been designed and synthesized via a hydrothermal method. All three compounds exhibited similar two-dimensional (2D)… read more here.
Keywords: proton conduction; organic rotaxane; based metal; metal organic ... See more keywords