Metal Sulfide Photocatalysis: Visible‐Light‐Induced Organic Transformations
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201801773
Abstract: Transition‐metal sulfides belong to an important subgroup of semiconductor photocatalysts that could promote a variety of valuable redox reactions under mild conditions. One notable merit of metal sulfides is their relatively smaller bandgaps than metal… read more here.
Keywords: organic transformations; light induced; visible light; metal sulfides ... See more keywords
Carbazolic Conjugated Microporous Polymers for Photocatalytic Organic Transformations.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202300012
Abstract: Heterogeneous photocatalysis have been deemed as a versatile and colorful platform for exploring efficient transformation systems. Henceforth, the design of photocatalysts underpin a wide range of research interests. By virtue of synthetic versatility, stability, non-toxicity,… read more here.
Keywords: conjugated microporous; photocatalytic organic; carbazolic conjugated; microporous polymers ... See more keywords
Organic transformations using electro-generated polyoxometalate redox mediators
Sign Up to like & getrecommendations! Published in 2021 at "Catalysis Today"
DOI: 10.1016/j.cattod.2021.05.003
Abstract: Abstract The use of electrochemistry in organic synthesis (sometimes termed electro-organic synthesis, or just “electrosynthesis”) is a field that is attracting ever-increasing attention on account of its ability to deliver reaction outcomes that cannot be… read more here.
Keywords: redox; electro organic; organic synthesis; electro generated ... See more keywords
XtalFluor-E: A useful and versatile reagent in organic transformations
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2019.06.006
Abstract: Abstract XtalFluor-E, [Et2NSF2]BF4, is best known as a useful, versatile and inexpensive commercially available reagent for the deoxyfluorination of carbonyl compounds and alcohols. Although XtalFluor-E is commonly used in combination with an exogenous fluoride source… read more here.
Keywords: reagent organic; useful versatile; xtalfluor useful; reagent ... See more keywords
SO3H-functionalized porous organic polymer with amphiphilic and swelling properties: A highly efficient solid acid catalyst for organic transformations in water
Sign Up to like & getrecommendations! Published in 2020 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2020.110110
Abstract: Abstract SO3H-Functionalized porous organic polymers were successfully synthesized by a solvothermal, free radical copolymerization, and successive ion exchange method. Physicochemical characterizations suggested that the prepared polymers featured relatively large surface areas, large pore volumes, excellent… read more here.
Keywords: solid acid; catalyst; organic transformations; water ... See more keywords
Structural engineering of 2D covalent organic frameworks for visible-light-driven organic transformations.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c00013
Abstract: Covalent organic frameworks (COFs) emerging as a novel kind of visible light responsive organic semiconductors have attracted extensive research attentions in the field of photocatalytic organic transformations. However, the key parameters affecting their photocatalytic properties… read more here.
Keywords: organic transformations; visible light; light driven; organic frameworks ... See more keywords
Strategies for Incorporating Catalytically Active Polyoxometalates in Metal-Organic Frameworks for Organic Transformations.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b19785
Abstract: Polyoxometalates (POMs) can benefit from immobilization on solid supports to overcome their difficulty in processability and stability. Among the reported solid supports, metal-organic frameworks (MOFs) offer a crystalline, versatile platform for depositing highly active POMs.… read more here.
Keywords: catalytically active; organic transformations; strategies incorporating; incorporating catalytically ... See more keywords
Photocatalytic metal–organic frameworks for organic transformations
Sign Up to like & getrecommendations! Published in 2017 at "CrystEngComm"
DOI: 10.1039/c7ce00398f
Abstract: Metal–organic frameworks (MOFs) have attracted increasing attention for applications in heterogeneous photocatalysis. Modifications of metal nodes and organic linkers, as well as encapsulation of active species in the pores of MOFs enable the generation of… read more here.
Keywords: photocatalytic metal; organic transformations; metal organic; metal ... See more keywords
Mechanisms of photoredox catalysts: the role of optical spectroscopy
Sign Up to like & getrecommendations! Published in 2021 at "Sustainable Energy and Fuels"
DOI: 10.1039/d0se01454k
Abstract: Photoinduced organic transformations have stimulated the organic chemistry community to develop light-driven renewed reaction methodologies, which in many cases are complementary to standard thermal catalysis. This revitalization of photoinduced transformations is in part due to… read more here.
Keywords: spectroscopy; photoredox catalysts; optical spectroscopy; energy ... See more keywords
Porous organic polymers for light-driven organic transformations.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d1cs00808k
Abstract: As a new generation of porous materials, porous organic polymers (POPs), have recently emerged as a powerful platform of heterogeneous photocatalysis. POPs are constructed using extensive organic synthesis methodologies, with various functional organic units being… read more here.
Keywords: organic polymers; driven organic; porous organic; organic transformations ... See more keywords
MOF/POM hybrids as catalysts for organic transformations.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01895k
Abstract: Insertion of molecular metal oxides, e.g. polyoxometalates (POMs), into metal-organic frameworks (MOFs) opens up new research opportunities in various fields, particularly in catalysis. POM/MOF composites have strong acidity, oxygen-rich surface, and redox capacity due to… read more here.
Keywords: hybrids catalysts; catalysts organic; pom hybrids; organic transformations ... See more keywords