Four-Coordinate Organoboron Platforms for Efficient Red Phosphorescent Organic Light-Emitting Diodes.
Sign Up to like & getrecommendations! Published in 2019 at "ChemPlusChem"
DOI: 10.1002/cplu.201900406
Abstract: So far both three- and four-coordinate organoboron compounds have been widely applied in organic light-emitting diode (OLED) materials. However, the use of four-coordinate organoboron compounds as host materials is rarely reported. In this work, two… read more here.
Keywords: organoboron; coordinate organoboron; four coordinate; organoboron compounds ... See more keywords
1,4-Phenylene-bis-((1-methyl-1H-pyrazol-5-yl)borinic 8-oxyquinolinate) as a photoredox catalyst in the atom transfer radical addition of iodoperfluoroalkanes to alkenyl groups bearing organoboron compounds
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.06.032
Abstract: Abstract The key photocatalytic properties of a transition-metal-free heteroleptic complex derived from 1,4-phenyldiboronic acid were evaluated. This compound was utilized in the atom transfer radical addition of iodoperfluoroalkanes to a series of alkenyl group bearing… read more here.
Keywords: bearing organoboron; radical addition; transfer radical; atom transfer ... See more keywords
Accessible approaches for vibrational zero point energy calculation of organoboron compounds
Sign Up to like & getrecommendations! Published in 2020 at "Vibrational Spectroscopy"
DOI: 10.1016/j.vibspec.2020.103131
Abstract: Abstract In this paper, two empirical approaches were used to calculate vibrational zero-point energies (ZPEs) of organoboron compounds. Firstly, the contribution of boron atom has been determined and incorporated in the Schulman and Disch empirical… read more here.
Keywords: approaches vibrational; organoboron compounds; vibrational zero; zero point ... See more keywords
Organoboron compounds constructed through the tautomerization of 1H-indole to 3H-indole for red OLEDs
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Materials Chemistry C"
DOI: 10.1039/d1tc01537k
Abstract: Through the tautomerization of 1H-indole to 3H-indole caused by triphenylboron, the electron-accepting 3H-indole group and the electron-donating N atom of an arylamino group are integrated into a π-conjugated fused-ring skeleton. The special π-skeleton endows the… read more here.
Keywords: organoboron compounds; tautomerization indole; red oleds; indole indole ... See more keywords
Bringing out the potential of organoboron compounds by designing the chemical bonds and spaces around boron.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00653g
Abstract: Since the structures, reactivity and properties of organoboron compounds stem from the electron deficiency and low electronegativity of boron, the design of the chemical bonds attached to boron as well as the space provided by… read more here.
Keywords: chemical bonds; organoboron compounds; potential organoboron; boron ... See more keywords
Computational thermochemistry: extension of Benson group additivity approach to organoboron compounds and reliable predictions of their thermochemical properties.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02659g
Abstract: High-level computational data for standard gas phase enthalpies of formation, entropies, and heat capacities are reported for 116 compounds of boron. A comparison of the results with extant experimental and computational benchmark values reveals important… read more here.
Keywords: group; group additivity; benson group; organoboron compounds ... See more keywords
Electrochemical Synthesis and Transformation of Organoboron Compounds
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00486d
Abstract: Organoboron compounds possess widespread applications in organic synthesis as well as pharmacuetical science and materials science. With the rapid development of organic electrochemistry, electrochemical borylation and hydroboration have emerged as... read more here.
Keywords: electrochemical synthesis; synthesis transformation; organoboron; organoboron compounds ... See more keywords
Supported Palladium Nanoparticles Catalyzed Intermolecular Carbopalladation of Nitriles and Organoboron Compounds
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.855850
Abstract: The first heterogeneous catalyzed example for the direct synthesis of aromatic ketones via intermolecular carbopalladation of aliphatic nitriles and organoboron compounds was developed. This mild method proceeds with a supported palladium nanoparticles catalyst that could… read more here.
Keywords: nitriles organoboron; palladium nanoparticles; supported palladium; organoboron compounds ... See more keywords
Recent Synthesis Developments of Organoboron Compounds via Metal-Free Catalytic Borylation of Alkynes and Alkenes
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DOI: 10.3390/molecules24010101
Abstract: Diboron reagents have been traditionally regarded as “Lewis acids”, which can react with simple Lewis base to create a significant nucleophilic character in one of boryl moieties. In particular, bis(pinacolato)diboron (B2pin2) reacts with simple Lewis… read more here.
Keywords: alkynes alkenes; organoboron compounds; free catalytic; recent synthesis ... See more keywords
Organoboron Compounds: Effective Antibacterial and Antiparasitic Agents
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26113309
Abstract: The unique electron deficiency and coordination property of boron led to a wide range of applications in chemistry, energy research, materials science and the life sciences. The use of boron-containing compounds as pharmaceutical agents has… read more here.
Keywords: organoboron compounds; antiparasitic agents; antibacterial antiparasitic; effective antibacterial ... See more keywords