Effects of Electronic Structure of Adjacent Carbon on the Strength of C─F⋯H─F Organofluorine Hydrogen Bonds
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DOI: 10.1002/jcc.26022
Abstract: We investigate the effects of the electronic structure of carbon atom on the organofluorine hydrogen bonds, C─F⋯H─F. Our results show that we can modulate the strength of organofluorine hydrogen bonds by adjusting the volume of… read more here.
Keywords: carbon; hydrogen; hydrogen bonds; strength organofluorine ... See more keywords
Understanding the effects of vicinal carbon substituents and configuration on organofluorine hydrogen-bonding interaction
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DOI: 10.1039/c8ra08122k
Abstract: An investigation of C–F⋯H–O hydrogen bonds in the complexes CHnXCHnF⋯H2O (n = 0, 1, 2; X = H, F, Cl, Br) was performed at the MP2/aug-cc-pVTZ level. We found that the electron-withdrawing halogen substituents on… read more here.
Keywords: hydrogen; bond; vicinal carbon; interaction ... See more keywords