Preparation of Highly Reactive Lithium Metal Dendrites for the Synthesis of Organolithium Reagents.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07207
Abstract: A long-standing problem in the area of organolithium chemistry has been the need for a highly reactive Li-metal source that mimics Li-powders but has the advantage of being freshly prepared from inexpensive and readily available… read more here.
Keywords: synthesis organolithium; preparation; organolithium reagents; metal ... See more keywords
Cu-catalyzed enantioselective allylic alkylation with organolithium reagents
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DOI: 10.1038/nprot.2016.179
Abstract: This protocol describes a method for the catalytic enantioselective synthesis of tertiary and quaternary carbon stereogenic centers, which are widely present in pharmaceutical and natural products. The method is based on the direct reaction between… read more here.
Keywords: organolithium reagents; allylic alkylation; catalyzed enantioselective; enantioselective allylic ... See more keywords
Recent Advances in NMR: Aggregation, Solvation, and Dynamics of Selected Organolithium Compounds
Sign Up to like & getrecommendations! Published in 2018 at "Synthesis"
DOI: 10.1055/s-0037-1610162
Abstract: Nuclear magnetic resonance (NMR) spectroscopy is the most widely used analytical technique to study the structure and dynamics of organolithium compounds, which are the most popular reagents in organic synthesis due to their great diversity… read more here.
Keywords: aggregation; solvation; 6li isotope; recent advances ... See more keywords