Preparation of Highly Reactive Lithium Metal Dendrites for the Synthesis of Organolithium Reagents.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07207
Abstract: A long-standing problem in the area of organolithium chemistry has been the need for a highly reactive Li-metal source that mimics Li-powders but has the advantage of being freshly prepared from inexpensive and readily available… read more here.
Keywords: synthesis organolithium; preparation; organolithium reagents; metal ... See more keywords
Cu-catalyzed enantioselective allylic alkylation with organolithium reagents
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DOI: 10.1038/nprot.2016.179
Abstract: This protocol describes a method for the catalytic enantioselective synthesis of tertiary and quaternary carbon stereogenic centers, which are widely present in pharmaceutical and natural products. The method is based on the direct reaction between… read more here.
Keywords: organolithium reagents; allylic alkylation; catalyzed enantioselective; enantioselective allylic ... See more keywords
Synthesis of 3–aryl 3–hydroxyisoindolinones by the Addition of Grignard and Organolithium Reagents to Phthalimides
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DOI: 10.2174/1385272821666170222100150
Abstract: DOI: 10.2174/1385272821666170222100150 Abstract: Background: The 3-substituted 3-hydroxyisoindolinone motif is common to a variety of compounds with potent biological activities. In recent years, they have also been increasingly used as substrates in various asymmetric transformations. Current… read more here.
Keywords: aryl hydroxyisoindolinones; hydroxyisoindolinones addition; organolithium reagents; grignard organolithium ... See more keywords