Organometallic catalysis in biological media and living settings
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DOI: 10.1016/j.ccr.2018.01.011
Abstract: Abstract Organometallic catalysis has allowed the development of an impressive number of chemical transformations that could not be achieved using classical methodologies. Most of these reactions have been accomplished in organic solvents, and in many… read more here.
Keywords: organometallic catalysis; chemistry; metal; biological media ... See more keywords
A generalized kinetic model for compartmentalization of organometallic catalysis
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DOI: 10.1039/d1sc04983f
Abstract: Compartmentalization is an attractive approach to enhance catalytic activity by retaining reactive intermediates and mitigating deactivating pathways. Such a concept has been well explored in biochemical and more recently, organometallic catalysis to ensure high reaction… read more here.
Keywords: chemistry; organometallic catalysis; compartmentalization; kinetic model ... See more keywords
Organometallic catalysis in aqueous and biological environments: harnessing the power of metal carbenes
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DOI: 10.1039/d2sc00721e
Abstract: Translating the power of transition metal catalysis to the native habitats of enzymes can significantly expand the possibilities of interrogating or manipulating natural biological systems, including living cells and organisms. This is especially relevant for… read more here.
Keywords: power; aqueous biological; catalysis aqueous; organometallic catalysis ... See more keywords