Organometallic chemistry: A shortcut to molecular complexity.
Sign Up to like & getrecommendations! Published in 2017 at "Nature chemistry"
DOI: 10.1038/nchem.2750
Abstract: A unique transformation for the site-selective cleavage of one C–C single bond and two C–H bonds in sequence has now been developed. This enables a simple carbon skeleton to be reorganized into a significantly more… read more here.
Keywords: shortcut molecular; chemistry; molecular complexity; organometallic chemistry ... See more keywords
Organometallic chemistry using partially fluorinated benzenes.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c6cc09575e
Abstract: Fluorobenzenes, in particular fluorobenzene (FB) and 1,2-difluorobenzene (1,2-DiFB), are increasingly becoming recognised as versatile solvents for conducting organometallic chemistry and transition-metal-based catalysis. The presence of fluorine substituents reduces the ability to donate π-electron density from… read more here.
Keywords: partially fluorinated; fluorinated benzenes; chemistry; using partially ... See more keywords
Organometallic chemistry in aqua regia: metal and ligand based oxidations of (NHC)AuCl complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04472h
Abstract: The synthesis and characterization of a series of N-heterocyclic carbene (NHC) complexes of Au(iii), (NHC)AuCl3, is described. High yields are obtained when the corresponding Au(i) species (NHC)AuCl are oxidized with inexpensive aqua regia. The oxidation… read more here.
Keywords: nhc aucl; aqua regia; chemistry; organometallic chemistry ... See more keywords
Molecular-level insight in supported olefin metathesis catalysts by combining surface organometallic chemistry, high throughput experimentation, and data analysis† †Electronic supplementary information (ESI) available. See DOI: 10.1039/d0sc02594a
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc02594a
Abstract: Combination of high-throughput experimentation, surface organometallic chemistry and data analysis helps to extract key structural parameters that facilitate olefin metathesis. read more here.
Keywords: data analysis; surface organometallic; chemistry; throughput experimentation ... See more keywords
Olefin metathesis: what have we learned about homogeneous and heterogeneous catalysts from surface organometallic chemistry?†
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d0sc06880b
Abstract: Since its early days, olefin metathesis has been in the focus of scientific discussions and technology development. While heterogeneous olefin metathesis catalysts based on supported group 6 metal oxides have been used for decades in… read more here.
Keywords: surface organometallic; chemistry; olefin metathesis; organometallic chemistry ... See more keywords
Organometallic chemistry and application of palladacycles in asymmetric hydrophosphination reactions.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt03134a
Abstract: A number of palladacycles containing chiral chelating auxiliaries have been utilized as efficient catalysts for asymmetric hydrophosphination reactions. In all cases, the chiral auxiliaries remained coordinated to the palladium centres throughout the course of the… read more here.
Keywords: hydrophosphination reactions; asymmetric hydrophosphination; chemistry; chemistry application ... See more keywords
Organometallic chemistry confined within a porphyrin-like framework.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Society reviews"
DOI: 10.1039/d2cs00784c
Abstract: The world of modified porphyrins changed forever when an N-confused porphyrin (NCP), a porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a carbon atom revolutionised the chemistry that one… read more here.
Keywords: chemistry; porphyrin like; confined within; chemistry confined ... See more keywords
Supramolecular organometallic chemistry: the platinum(IV) paradigm.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00872f
Abstract: Supramolecular chemistry and the chemistry of alkyl derivatives of the transition metals are both topics of considerable current interest, but the combination of the two fields is still underdeveloped. The challenges are, in large part,… read more here.
Keywords: chemistry platinum; chemistry; supramolecular chemistry; platinum ... See more keywords
Editorial for “Organometallic Chemistry” Section, in Journal Molecules
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25133038
Abstract: It is a great pleasure to assume the role of Editor-in-Chief for the "Organometallic Chemistry" Section of Molecules (https://www [...]. read more here.
Keywords: chemistry; chemistry section; molecules editorial; editorial organometallic ... See more keywords
Guanidinates as Alternative Ligands for Organometallic Complexes
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27185962
Abstract: For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have dominated Coordination and Organometallic Chemistry. At the same time, alternative compounds have emerged that could compete either for a more practical and accessible synthesis… read more here.
Keywords: ligands organometallic; organometallic complexes; guanidinates alternative; chemistry ... See more keywords
Organometallic Chemistry within the Structured Environment Provided by the Macrocyclic Cores of Carbaporphyrins and Related Systems
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031496
Abstract: The unique environment within the core of carbaporphyrinoid systems provides a platform to explore unusual organometallic chemistry. The ability of these structures to form stable organometallic derivatives was first demonstrated for N-confused porphyrins but many… read more here.
Keywords: chemistry within; chemistry; within structured; structured environment ... See more keywords