Intracellular delivery of a catalytic organometallic complex.
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DOI: 10.1039/c7cc02988h
Abstract: A homogeneous carbene-based palladium catalyst was conjugated to a cell-penetrating peptide, allowing intracellular delivery of catalytically active Pd complexes that demonstrated bioorthogonal activation of a profluorophore within prostate cancer cells. read more here.
Keywords: delivery catalytic; delivery; catalytic organometallic; intracellular delivery ... See more keywords
The first ReI organometallic complex with an organoimido-polyoxometalate ligand.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01633f
Abstract: The spectroscopic, electrochemical and photophysical properties of the first ReI organometallic organoimido-polyoxometalate complex [n-Bu4N][Mo6O18NC6H4-CH2-N3C2H2-Re-phen(CO)3] compared with all fragments are reported. The UV-Vis spectra are analysed using experimental and theoretical tools. In contrast to the reported… read more here.
Keywords: polyoxometalate; rei organometallic; organoimido polyoxometalate; first rei ... See more keywords
Smooth and large scale organometallic complex film by vapor-phase ligand exchange reaction
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DOI: 10.1039/d0ra00403k
Abstract: A simple and reliable method for the formation of smooth and large-scale organometallic complex thin films was developed. We applied chemical vapor deposition (CVD) for this. From the vapor-phase reaction of Mo(CO)6 and 2,2′-bipyridine, large-scale… read more here.
Keywords: large scale; scale organometallic; vapor; smooth large ... See more keywords
Light-driven oxidation of CH4 to C1 chemicals catalysed by an organometallic Ru complex with O2
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra01772e
Abstract: CH4 conversion is one of the most challenging chemical reactions due to its inertness in terms of physical and chemical properties. We have achieved photo-induced C–H bond breaking of CH4 and successive C–O bond formation… read more here.
Keywords: ch4; driven oxidation; oxidation ch4; ch4 chemicals ... See more keywords