Articles with "organometallic complexes" as a keyword



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Organometallic complexes of carbon nanotori

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Published in 2019 at "Journal of Molecular Modeling"

DOI: 10.1007/s00894-019-4118-0

Abstract: New organometallic complexes of carbon nanotori were designed and theoretically described by means of density functional theory. After a systematic structural search, it was found that energetically favorable complexes were formed by the metal atoms… read more here.

Keywords: nanotorus; carbon; organometallic complexes; complexes carbon ... See more keywords
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In vitro leishmanicidal activity and theoretical insights into biological action of ruthenium(II) organometallic complexes containing anti-inflammatories

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Published in 2018 at "BioMetals"

DOI: 10.1007/s10534-018-0145-z

Abstract: Leishmaniasis, a neglected tropical disease caused by protozoans of the genus Leishmania, kills around 20–30 thousand people in Africa, Asia, and Latin America annually and, despite its potential lethality, it can be treated and eventually… read more here.

Keywords: ruthenium organometallic; organometallic complexes; complexes containing; leishmanicidal activity ... See more keywords
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Electric and magnetic properties of cobalt, copper and nickel organometallic complexes for molecular wires

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Published in 2021 at "Ain Shams Engineering Journal"

DOI: 10.1016/j.asej.2020.12.002

Abstract: Abstract This research aims at the electric and magnetic characterization of specific organometallic complexes for the purpose of using them as molecular wires confined in specific channels that can find applications in electronic systems. The… read more here.

Keywords: copper nickel; electric magnetic; organometallic complexes; molecular wires ... See more keywords
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Synthesis, Structure, Electrochemical, and Spectroscopic Properties of Hetero-Bimetallic Ru(II)/Fe(II)-Alkynyl Organometallic Complexes.

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Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.8b02440

Abstract: A series of heterobimetallic wire-like organometallic complexes [( tpy-C6H4-R)(PPh3)2Ru-C≡C-Fc]+ ( tpy-C6H4-R = 4'-(aryl)-2,2':6',2''-terpyridyl, Fc = [(η5-Cp)2Fe], R = -H, -Me, -F, -NMe2 in complexes 5-8, respectively) featuring ferrocenyl and 4'-(aryl)-2,2':6',2''-terpyridyl ruthenium(II) complexes as redox active… read more here.

Keywords: structure electrochemical; organometallic complexes; spectroscopic properties; spectroscopic ... See more keywords
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Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

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Published in 2020 at "Organometallics"

DOI: 10.1021/acs.organomet.0c00096

Abstract: The preparation of dinuclear aluminum and gallium complexes with controlled M···M proximity (intermetal separation of 3.28–4.35 A) was achieved through direct chelation of the multidentate bis(diph... read more here.

Keywords: dinuclear organometallic; linkage isomerism; organometallic complexes; complexes structural ... See more keywords
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Aqua-friendly organometallic Ir-Pt complexes: pH-responsive AIPE-guided imaging of bacterial cells.

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Published in 2023 at "Dalton transactions"

DOI: 10.1039/d2dt03390a

Abstract: In this work, the aggregation-induced photoluminescence emission (AIPE) of three water-soluble heterobimetallic Ir-Pt complexes was reported with insight into their photophysical and electrochemical properties and imaging of bacterial cells. An alkyne appended Schiff's base L,… read more here.

Keywords: imaging bacterial; organometallic complexes; aqua friendly; friendly organometallic ... See more keywords
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Rhodium and Iridium Mediated C-H and O-H Bond Activation of Two Schiff Base Ligands: Synthesis, Characterization and Catalytic Properties of the Organometallic Complexes

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Published in 2021 at "Frontiers in Chemistry"

DOI: 10.3389/fchem.2021.696460

Abstract: Reaction of [Rh(PPh3)3Cl] with two Schiff base ligands, viz. N-(2′-hydroxyphenyl)furan-2-aldimine (H 2 L 1 ) and N-(2′-hydroxyphenyl)thiophene-2-aldimine (H 2 L 2 ), in refluxing toluene affords organorhodium complexes of type [Rh(PPh3)2(L)Cl] (L = L1 and… read more here.

Keywords: base ligands; organometallic complexes; bond activation; two schiff ... See more keywords
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Guanidinates as Alternative Ligands for Organometallic Complexes

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27185962

Abstract: For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have dominated Coordination and Organometallic Chemistry. At the same time, alternative compounds have emerged that could compete either for a more practical and accessible synthesis… read more here.

Keywords: ligands organometallic; organometallic complexes; guanidinates alternative; chemistry ... See more keywords