Diazo compounds and palladium-aryl complexes: trapping the elusive carbene migratory insertion organometallic products.
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DOI: 10.1039/d2dt02775e
Abstract: The reactions of Pd-aryl complexes with diazo compounds N2CH-CHCHPh and N2CHPh allowed us to isolate the organometallic products formed right after the migratory insertion of a non-stabilized CHR carbene into the Pd-aryl bond. η3-Allylic and… read more here.
Keywords: migratory insertion; aryl complexes; diazo compounds; organometallic products ... See more keywords