Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes.
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DOI: 10.1021/acs.orglett.2c03366
Abstract: gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were… read more here.
Keywords: gem; enables synthesis; gem fluorophosphonate; organophotocatalysis enables ... See more keywords