Thermodynamic modeling of the deposition of Si—C—N films from the gas phase during the decomposition of organosilicon compounds
Sign Up to like & getrecommendations! Published in 2018 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-018-2167-7
Abstract: Thermodynamic modeling of the process of chemical vapor deposition (CVD) of SiCx and SiCxNy films from the gas phase was carried out using organosilicon compounds (EtN(SiMe3)2, PhN(SiMe3)2, and PhSiMe3) at reactor pressures of 0.01 and… read more here.
Keywords: phase; deposition; films gas; thermodynamic modeling ... See more keywords
The Formation of C-C or C-N Bonds via the Copper-Catalyzed Coupling of Alkylsilyl Peroxides and Organosilicon Compounds: A Route to Perfluoroalkylation.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c00215
Abstract: The copper-catalyzed selective cleavage of alkylsilyl peroxides and the subsequent formation of carbon-carbon or carbon-nitrogen bonds with organosilicon compounds are described. The reaction proceeds under mild conditions and exhibits a broad substrate scope with respect… read more here.
Keywords: carbon; alkylsilyl; alkylsilyl peroxides; organosilicon compounds ... See more keywords
Reactivity of Waterlogged Archeological Elm Wood with Organosilicon Compounds Applied as Wood Consolidants: 2D 1H–13C Solution-State NMR Studies
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27113407
Abstract: Some organosilicon compounds, including alkoxysilanes and siloxanes, proved effective in stabilizing the dimensions of waterlogged archaeological wood during drying, which is essential in the conservation process of ancient artifacts. However, it was difficult to determine… read more here.
Keywords: state nmr; organosilicon compounds; 13c solution; reactivity ... See more keywords
Chemical Recycling of High-Molecular-Weight Organosilicon Compounds in Supercritical Fluids
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym14235170
Abstract: The main known patterns of thermal and/or catalytic destruction of high-molecular-weight organosilicon compounds are considered from the viewpoint of the prospects for processing their wastes. The advantages of using supercritical fluids in plastic recycling are… read more here.
Keywords: organosilicon compounds; molecular weight; weight organosilicon; supercritical fluids ... See more keywords