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Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03294k
Abstract: Transition-metal-catalyzed carbonylation provides a useful approach to synthesize carbonyl-containing compounds and their derivatives. Controlling the regio-, chemo-, and stereoselectivity remains a significant challenge and is the key to the success of transformation. In the present…
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Keywords:
mechanism origins;
mechanism;
regiodivergent carbonylation;
origins ligand ... See more keywords
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Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj05515k
Abstract: DFT calculations demonstrated that the bulky ligand tBuPPh2 generates para-substituted products, while the small ligand Me2PPh provides ortho-substituted products.
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Keywords:
mechanism origins;
dft;
origins ligand;
study mechanism ... See more keywords