Nickel-Catalyzed, Manganese-Assisted Denitrogenative Cross-Electrophile-Coupling of Benzotriazinones with Alkyl Halides for ortho-Alkylated Benzamides.
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DOI: 10.1021/acs.orglett.2c02182
Abstract: A nickel-catalyzed denitrogenative cross-electrophile-coupling of benzotriazinones with unactivated alkyl halides (X = Cl, Br, I) in the presence of manganese powder as a reductant has been developed. The reaction furnishes ortho-alkylated secondary benzamides in modest… read more here.
Keywords: ortho alkylated; denitrogenative cross; nickel catalyzed; electrophile coupling ... See more keywords