Enhancing Suppression of Chain Transfer via Installing Bulky N‐ortho‐Aryl Substituents into α‐Diimine Nickel System
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DOI: 10.1002/cctc.202400619
Abstract: Recently, the important role of sterically bulky aromatic substituents at the axial position of the metal center for synthesizing high‐performance catalysts were recognized. In this study, a series of α‐diimine nickel complexes with bulky N‐ortho‐aryl… read more here.
Keywords: nickel complexes; ortho aryl; diimine nickel; aryl substituents ... See more keywords
On the topology of highly branched polyethylenes prepared by amine−imine nickel and palladium complexes: the effect of ortho‐aryl substituents
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DOI: 10.1002/pi.5593
Abstract: Series of nickel and palladium complexes bearing amine-imine ligands in various ortho-aryl and backbone positions were prepared and investigated in ethene polymerization. Ethene polymerization initiated by symmetrically ortho-substituted nickel and palladium amine-imine catalysts is controlled.… read more here.
Keywords: topology; ortho aryl; nickel palladium; amine imine ... See more keywords